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695904

Sigma-Aldrich

1,3-Butadiene

15 wt. % in hexane

Sinonimo/i:

Bivinyl, Vinylethylene, alpha,gamma-Butadiene

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About This Item

Formula empirica (notazione di Hill):
C4H6
Numero CAS:
106-99-0
Peso molecolare:
54.09
Numero MDL:
MFCD00008659
Codice UNSPSC:
12352100
ID PubChem:
329761784
NACRES:
NA.22

Forma fisica

liquid

Concentrazione

15 wt. % in hexane

Indice di rifrazione

n20/D 1.376

Densità

0.682 g/mL at 25 °C

Temperatura di conservazione

2-8°C

Stringa SMILE

C=CC=C

InChI

1S/C4H6/c1-3-4-2/h3-4H,1-2H2
KAKZBPTYRLMSJV-UHFFFAOYSA-N

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Categorie correlate

Applicazioni

1,3-Butadiene can be used as a monomer to synthesize polybutadiene with one hydroxy end group and other silyl hydroxy-protecting end group, a precursor for two-step synthesis of hydroxyl-terminated polybutadiene (HTPB).

Avvertenze

Danger

Classi di pericolo

Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Muta. 1B - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3

Organi bersaglio

Central nervous system, Nervous system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

-105.0 °F

Punto d’infiammabilità (°C)

-76.11 °C

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

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Synthesis of hydroxyl-terminated polybutadiene bearing pendant carboxyl groups by combination of anionic polymerization and blue light photocatalytic thiol-ene reaction and its pH-triggered self-assemble behavior.
Zhang W, et al.
Reactive and Functional Polymers, 127, 161-167 (2018)
Xin Min et al.
Royal Society open science, 5(5), 180156-180156 (2018-06-13)
A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized. By using TBDMSODPrLi, hydroxyl-terminated polybutadiene (HTPB) was prepared via anionic polymerization. The macromolecular structure of HTPB was characterized and verified by FTIR and
Dewakar Sangaraju et al.
Analytical chemistry, 84(3), 1732-1739 (2012-01-10)
1,3-Butadiene (BD) is an important industrial chemical and a common environmental pollutant present in urban air. BD is classified as a human carcinogen based on epidemiological evidence for an increased incidence of leukemia in workers occupationally exposed to BD and
Christopher R Kirman et al.
Critical reviews in toxicology, 40 Suppl 1, 74-92 (2010-09-28)
1,3-Butadiene (BD) is a multisite carcinogen in laboratory rodents following lifetime exposure, with greater potency in the mouse than the rat, and is associated with an increase in leukemia mortality in highly exposed workers. Species differences in the formation of
Gunnar Boysen et al.
Toxicological sciences : an official journal of the Society of Toxicology, 125(1), 30-40 (2011-10-18)
1,3-Butadiene (BD) is an important industrial chemical that is classified as a human carcinogen. BD carcinogenicity has been attributed to its metabolism to several reactive epoxide metabolites and formation of the highly mutagenic 1,2:3,4-diepoxybutane (DEB) has been hypothesized to drive
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