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372439

Sigma-Aldrich

Perfluoro(methyldecalin), mixture of isomers

technical grade, 80%

Sinonimo/i:

Heptadecafluorodecahydro(trifluoromethyl)naphthalene

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About This Item

Formula empirica (notazione di Hill):
C11F20
Numero CAS:
51294-16-7
Peso molecolare:
512.09
Codice UNSPSC:
12352100
ID PubChem:
24863035
NACRES:
NA.22
Prezzi e disponibilità al momento non sono disponibili

Grado

technical grade

Saggio

80%

Stato

liquid

Indice di rifrazione

n20/D 1.317 (lit.)

P. ebollizione

137-160 °C (lit.)

Punto di fusione

−40 °C (lit.)

Densità

1.95 g/mL at 25 °C (lit.)

Stringa SMILE

FC(F)(F)C1(F)C(F)(F)C(F)(F)C2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C1(F)F.FC(F)(F)C3(F)C(F)(F)C(F)(F)C(F)(F)C4(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C34F

InChI

1S/C11F20/c12-1-2(13,6(19,20)10(27,28)9(25,26)4(1,15)16)5(17,18)8(23,24)7(21,22)3(1,14)11(29,30)31
LWRNQOBXRHWPGE-UHFFFAOYSA-N

Categorie correlate

Descrizione generale

Perfluoro(methyldecalin) is a fluorinated solvent.[1]

Applicazioni

Perfluoro(methyldecalin is suitable reagent used to investigate the reactions of iodide anions and anions derived from glow discharge ionization of perfluoro(methyldecalin) with positive ions derived from poly(ethylene glycol).[2] It is suitable reagent used for the oxidation of alcohols with the ruthenium porphyrin at higher temperatures (140ºC) and elevated oxygen pressures (50psi).[1] Perfluoro(methyldecalin (Perfluoro-1-Methyldecalin) may be used in the preparation of undecafluoro-6-trifluoromethyltetralin via defluorination.[3]

Altre note

Contains perfluorodecalin

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

235.0 °F - closed cup

Punto d’infiammabilità (°C)

112.80 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves

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Certificati d'analisi (COA)

Lot/Batch Number
MKCR6988
MKCR2138
MKCP2231
MKCL3965
MKCK8963

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M K Bakulin et al.
Prikladnaia biokhimiia i mikrobiologiia, 43(4), 443-449 (2007-10-13)
The addition of perfluorocarbons (perfluorodecalin, carbogal, and perfluoromethyldecalin) to nitrogen-free liquid media during the submerged cultivation of bacteria of the genus Azotobacter was followed by (1) increases in biomass accumulation and nitrogenase activity and (2) fixation of molecular nitrogen. Addition
37. Polycyclic fluoroaromatic compounds. Part II. Perfluoromethylnaphthalenes and derived compounds.
Gething B, et al.
Journal of the Chemical Society, 190-193 (1962)
D J McIver et al.
Biochimica et biophysica acta, 751(1), 74-80 (1983-03-22)
An effective substitute for pulmonary surfactant must be able to reduce water-vapour surface tensions to under 1 mN/m and it must spread rapidly and spontaneously at the air interface from the aqueous phase. Pure dipalmitoylphosphatidylcholine meets the former requirement, but
Michinao Hashimoto et al.
Small (Weinheim an der Bergstrasse, Germany), 3(10), 1792-1802 (2007-09-25)
A method is described for the formation of stable, composite aqueous emulsions of 1) combinations of distinct families of bubbles of nitrogen, 2) combinations of distinct families of droplets of an organic fluid (either perfluoro(methyl)decalin or hexadecane), and 3) combinations
Vasily N Korotchenko et al.
Organic & biomolecular chemistry, 6(11), 1961-1965 (2008-05-16)
Carbonylruthenium tetrakis(pentafluorophenyl)porphyrin Ru(TPFPP)(CO) was utilized for the aerobic oxidation of alcohols. The in situ activation of the catalyst with mCPBA provided a species capable of catalyzing the oxidation of alcohols with molecular oxygen. The choice of solvent and additive was
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