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254142

Sigma-Aldrich

Bismuth(III) chloride

99.99% trace metals basis

Sinonimo/i:

Bismuth trichloride, Trichlorobismuth

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About This Item

Formula empirica (notazione di Hill):
BiCl3
Numero CAS:
7787-60-2
Peso molecolare:
315.34
Numero CE:
232-123-2
Numero MDL:
MFCD00003461
Codice UNSPSC:
12352302
ID PubChem:
24855360
NACRES:
NA.23

Saggio

99.99% trace metals basis

Forma fisica

solid

Impiego in reazioni chimiche

reagent type: catalyst
core: bismuth

Impurezze

≤150.0 ppm Trace Metal Analysis

P. eboll.

447 °C (lit.)

Punto di fusione

230-232 °C (lit.)

Stringa SMILE

Cl[Bi](Cl)Cl

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3
JHXKRIRFYBPWGE-UHFFFAOYSA-K

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Categorie correlate

Descrizione generale

Bismuth(III) chloride is a Lewis acid catalyst and a common source of Bi3+ ions used in various organic transformations and synthesis of bismuth nanomaterials.

Applicazioni

Bismuth(III) chloride can be used:
  • As a precursor to prepare polyaniline and bismuth(III) telluride nanohybrids with high thermoelectric performance.
  • As a starting material to synthesize visible light absorbing double perovskite semiconductors, such as Cs2AgBiBr6 and Cs2AgBiCl6, eco-friendly alternative to the lead halide perovskites.
  • To form a protective layer on anode materials.
It can also be used as an efficient catalyst for green synthesis of:
  • Chalcones by Claisen–Schmidt reaction under solvent-free conditions.
  • One-pot three-component synthesis of Propargylamines.
  • Coumarins via ultrasound‐assisted Pechmann condensation of phenols with β‐ketoesters.

Pittogrammi

Exclamation mark
GHS07

Avvertenze

Warning

Indicazioni di pericolo

H315,H319

Classi di pericolo

Eye Irrit. 2 - Skin Irrit. 2

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

Certificati d'analisi (COA)

Cerca il Certificati d'analisi (COA) digitando il numero di lotto/batch corrispondente. I numeri di lotto o di batch sono stampati sull'etichetta dei prodotti dopo la parola ‘Lotto’ o ‘Batch’.

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An efficient green protocol for the synthesis of chalcones by a Claisen-Schmidt reaction using bismuth (III) chloride as a catalyst under solvent-free condition
Dhruva Kumar, et al.
Green Chemistry Letters and Reviews, 3, 283-286 (2010)
Cs2AgBiX6 (X= Br, Cl): new visible light absorbing, lead-free halide perovskite semiconductors
Eric T McClure, et al.
Chemistry of Materials, 28, 1348-1354 (2016)
Organic-inorganic nanohybrids as novel thermoelectric materials: hybrids of polyaniline and bismuth (III) telluride nanoparticles
Naoki Toshima, et al.
Journal of Electronic Materials, 40, 898-902 (2011)
A bismuth-based protective layer for magnesium metal anode in noncorrosive electrolytes
Yimin Zhao, et al.
ACS Energy Letters, 6, 2594-2601 (2021)
A simple and efficient one-pot three-component synthesis of propargylamines using bismuth (III) chloride
Abbas Teimouri, et al.
Bulletin of the Korean Chemical Society,, 33, 1556-1560 (2012)
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