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124095

Sigma-Aldrich

1-Bromo-3-methylbutane

96%

Sinonimo/i:

Isoamyl bromide, Isopentyl bromide

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About This Item

Formula condensata:
(CH3)2CHCH2CH2Br
Numero CAS:
107-82-4
Peso molecolare:
151.04
Beilstein:
773652
Numero CE:
203-522-9
Numero MDL:
MFCD00000253
Codice UNSPSC:
12352100
ID PubChem:
24847596
NACRES:
NA.22
Prezzi e disponibilità al momento non sono disponibili

Saggio

96%

Stato

liquid

Indice di rifrazione

n20/D 1.4409 (lit.)

P. ebollizione

120-121 °C (lit.)

Punto di fusione

−112 °C (lit.)

Solubilità

H2O: slightly soluble at 16.5 °C (0.02g/100ml)
alcohol: miscible
diethyl ether: miscible

Densità

1.261 g/mL at 25 °C (lit.)

Gruppo funzionale

alkyl halide
bromo

Temperatura di conservazione

2-8°C

Stringa SMILE

CC(C)CCBr

InChI

1S/C5H11Br/c1-5(2)3-4-6/h5H,3-4H2,1-2H3
YXZFFTJAHVMMLF-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

1-Bromo-3-methylbutane is a low toxic bromosolvent[1].

Applicazioni

1-Bromo-3-methylbutane was used in the synthesis of 1-(3-methylbutyl)pyrrole[2]. It was used in the production of pentyl peroxy radical by direct photolysis production method[3]. It was also used as extraction solvent for determination of polycyclic aromatic hydrocarbons in water samples using liquid-liquid microextraction combined with gas chromatography-mass spectrometry[1].

Avvertenze

Danger

Indicazioni di pericolo

H225,H315,H319,H335,H411

Classi di pericolo

Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

71.6 °F - closed cup

Punto d’infiammabilità (°C)

22 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
MKCW5606
MKCV9014
MKCV8997
MKCR3859
MKCQ4445

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Mei-I Leong et al.
Journal of chromatography. A, 1217(34), 5455-5461 (2010-07-29)
A low toxic dispersive liquid-liquid microextraction (LT-DLLME) combined with gas chromatography-mass spectrometry (GC-MS) had been developed for the extraction and determination of 16 polycyclic aromatic hydrocarbons (PAHs) in water samples. In normal DLLME assay, chlorosolvent had been widely used as
Erin N Sharp et al.
The journal of physical chemistry. A, 112(7), 1445-1456 (2008-01-24)
Cavity ringdown spectra of the A-X electronic transition of all eight isomers of the pentyl peroxy radical are reported. Using the corresponding assignments from previously studied smaller alkyl peroxy radicals, assignments of origin bands are made for the pentyl peroxy
J Stephen Elmore et al.
Journal of agricultural and food chemistry, 56(15), 6173-6179 (2008-07-16)
Wheat flour from plants deficient in sulfur has been shown to contain substantially higher levels of free amino acids, particularly asparagine and glutamine, than flour from wheat grown where sulfur nutrition was sufficient. Elevated levels of asparagine resulted in acrylamide
Guilong Peng et al.
Archives of environmental contamination and toxicology, 70(3), 607-614 (2015-11-29)
A low toxic solvent-based vortex-assisted surfactant-enhanced emulsification liquid-liquid microextraction (LT-VSLLME) combined with graphite furnace atomic absorption spectrometry was developed for the extraction and determination of lead (Pb) in water samples. In the LT-VSLLME method, the extraction solvent was dispersed into
Peter Tieu et al.
Frontiers in chemistry, 8, 599-599 (2020-08-06)
Metal nanoparticle catalysts functionalized with small, well-defined organic ligands are important because such systems can provide a spatial control in the catalyst-substrate interactions. This article describes the synthesis, stability, and catalytic property evaluations of four different Pd nanoparticles capped with
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Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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