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Ceric ammonium nitrate promoted oxidation of oxazoles.

Organic letters (2006-11-17)
David A Evans, Pavel Nagorny, Risheng Xu
ZUSAMMENFASSUNG

The ceric ammonium nitrate promoted oxidations of 4,5-diphenyloxazoles and oxazoles with various substitution patterns have been investigated. This transformation results in the formation of the corresponding imide in good yield and tolerates a wide variety of functional groups and substituents on the oxazole moiety. [reaction: see text].

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

Sigma-Aldrich
Ammoniumcer(IV)-nitrat, ACS reagent, ≥98.5%
Sigma-Aldrich
Ammoniumcer(IV)-nitrat, puriss. p.a., ACS reagent, ≥98.5% (RT)
Sigma-Aldrich
Ammoniumcer(IV)-nitrat, ≥99.99% trace metals basis
Sigma-Aldrich
Ammoniumcer(IV)-nitrat, ≥98% (titration)