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Merck

240486

Sigma-Aldrich

2-Methyl-2-butanol

ReagentPlus®, ≥99%

Synonym(e):

tert-Amylalkohol, tert.-Amylalkohol

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5 ML
CHF 69.70
100 ML
CHF 97.10

CHF 69.70


Voraussichtliches Versanddatum13. Mai 2025


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5 ML
CHF 69.70
100 ML
CHF 97.10

About This Item

Lineare Formel:
CH3CH2C(CH3)2OH
CAS-Nummer:
Molekulargewicht:
88.15
Beilstein:
1361351
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.21
bp:
102 °C (lit.)

CHF 69.70


Voraussichtliches Versanddatum13. Mai 2025


Bulk-Bestellung anfordern

Dampfdichte

3 (vs air)

Qualitätsniveau

Dampfdruck

12 mmHg ( 20 °C)

Produktlinie

ReagentPlus®

Assay

≥99%

Form

liquid

Selbstzündungstemp.

819 °F

Expl.-Gr.

9 %

dilution

(for general lab use)

Brechungsindex

n20/D 1.405 (lit.)

bp

102 °C (lit.)

mp (Schmelzpunkt)

−12 °C (lit.)

Dichte

0.805 g/mL at 25 °C (lit.)

Funktionelle Gruppe

hydroxyl

SMILES String

CCC(C)(C)O

InChI

1S/C5H12O/c1-4-5(2,3)6/h6H,4H2,1-3H3

InChIKey

MSXVEPNJUHWQHW-UHFFFAOYSA-N

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Allgemeine Beschreibung

2-Methyl-2-butanol is a sterically hindered alcohol.

Anwendung

2-Methyl-2-butanol may be used as a solvent in the following processes:
  • Palladium (II)-catalyzed ortho-C–H olefination of phenylacetic acids.[1]
  • Rhodium-catalyzed direct C-H functionalization at the C7 position of N-pivaloylindoles.[2]

It may also be used in the preparation of 2-chloro-2-methylbutane by reacting with concentrated hydrochloric acid.[3]

Rechtliche Hinweise

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Central nervous system, Respiratory system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

68.9 °F - closed cup

Flammpunkt (°C)

20.5 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Rhodium?Catalyzed Regioselective C7?Functionalization of N?Pivaloylindoles.
Xu L, et al.
Angewandte Chemie (International Edition in English), 55(1), 321-325 (2016)
?-tert-alkylation of ketones: 2-tert-pentylcyclopentanone
Organic Syntheses, 62, 95-95 (1984)
General kinetic modeling of the selective hydrogenation of 2-methyl-3-butyn-2-ol over a commercial palladium-based catalyst.
Vernuccio S, et al.
Industrial & Engineering Chemistry Research, 54(46), 11543-11551 (2015)
Yoon Ju Cho et al.
Laboratory animal research, 27(3), 197-203 (2011-10-15)
Tribromoethanol (2,2,2-tribromoethanol, TBE) is a popular injectable anesthetic agent used in mice in Korea. Our goal was to assess the risks associated with side effects (lesions) in the abdominal cavity, especially at high doses. To understand the underlying pathophysiological changes
Molecular association and dynamics in n-pentanol and 2-methyl-2-butanol: Ultrasonic, dielectric and viscosity studies at various temperatures.
D'Aprano A, et al.
Molecular Physics, 55(2), 475-488 (1985)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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