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Merck

18122

Sigma-Aldrich

1-Butyl-3-methyl-imidazolium-hexafluorophosphat

greener alternative

for catalysis, ≥98.5% (T)

Synonym(e):

BMIMPF6

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About This Item

Empirische Formel (Hill-System):
C8H15F6N2P
CAS-Nummer:
Molekulargewicht:
284.18
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22

Qualität

for catalysis

Qualitätsniveau

Assay

≥98.5% (T)

Grünere Alternativprodukt-Eigenschaften

Safer Solvents and Auxiliaries
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Verunreinigungen

≤0.03% water

Brechungsindex

n20/D 1.41

Dichte

1.38 g/mL at 20 °C (lit.)

Anionenspuren

bromide (Br-): ≤10 mg/kg
chloride (Cl-): ≤10 mg/kg
nitrate (NO3-): ≤10 mg/kg
phosphate (PO43-): ≤10 mg/kg
sulfate (SO42-): ≤10 mg/kg

Grünere Alternativprodukt-Kategorie

SMILES String

F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1

InChI

1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1

InChIKey

IXQYBUDWDLYNMA-UHFFFAOYSA-N

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Allgemeine Beschreibung

1-Butyl-3-methylimidazolium hexafluorophosphate is a high-purity ionic liquid (HPIL) with low water and halogen content, which makes it an effective solvent for transition-metal-catalyzed reactions. Some of its other advantageous properties include hydrophobicity and lack of vapor pressure.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Piktogramme

Exclamation mark

Signalwort

Warning

H-Sätze

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Die Dokumentenbibliothek aufrufen

Solvent properties of the 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid
Carda?Broch, S., A. Berthod, and D. W. Armstrong
Analytical and Bioanalytical Chemistry, 375.2, 191-199 (2003)
Thermodynamic properties of 1-butyl-3-methylimidazolium hexafluorophosphate in the ideal gas state
Paulechka, Yauheni U., et al.
Journal of Chemical and Engineering Data, 48.3, 457-462 (2003)
Temperature-dependent microscopic solvent properties of `dry?and `wet?1-butyl-3-methylimidazolium hexafluorophosphate: correlation with ET (30) and Kamlet?Taft polarity scales
Baker, Sheila N., Gary A. Baker, and Frank V. Bright
Green Chemistry, 4.2, 165-169 (2002)
Olefin Metathesis in the Ionic Liquid 1?Butyl?3?methylimidazolium Hexafluorophosphate Using a Recyclable Ru Catalyst: Remarkable Effect of a Designer Ionic Tag
Yao, Qingwei, and Yiliang Zhang
Angewandte Chemie (International Edition in English), 42.29, 3395-3398 (2003)
The Negishi coupling: an update
Aldrichimica Acta, 38(3), 69-69 (2005)

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