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A8309

Sigma-Aldrich

Acethydrazid

90%

Synonym(e):

Acetylhydrazin, Essigsäurehydrazid

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About This Item

Lineare Formel:
CH3CONHNH2
CAS-Nummer:
1068-57-1
Molekulargewicht:
74.08
Beilstein:
506165
EG-Nummer:
213-948-7
MDL-Nummer:
MFCD00007610
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24891331
NACRES:
NA.22

Assay

90%

Form

flakes

Verunreinigungen

<10% acetic acid

bp

129 °C/18 mmHg (lit.)

mp (Schmelzpunkt)

58-68 °C (lit.)

SMILES String

CC(=O)NN

InChI

1S/C2H6N2O/c1-2(5)4-3/h3H2,1H3,(H,4,5)

InChIKey

OFLXLNCGODUUOT-UHFFFAOYSA-N

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Allgemeine Beschreibung

Acethydrazide is an organic building that undergo catalytic hydrogenation to produce N′-methyl acethydrazide (MAH).

Anwendung

Acethydrazide can be used in the synthesis of (E)-N′-(2-hydroxybenzylidene)acetohydrazide, an ONO pincer ligand.

Piktogramme

Skull and crossbonesHealth hazard
GHS06,GHS08

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Oral - Carc. 2 - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flammpunkt (°F)

235.4 °F - closed cup

Flammpunkt (°C)

113 °C - closed cup

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Analysenzertifikate (COA)

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Indol-3-Essigsäurehydrazid 97%

Sigma-Aldrich

I3777

Indol-3-Essigsäurehydrazid

Oxalsäure-dihydrazid 98%

Sigma-Aldrich

131296

Oxalsäure-dihydrazid

N E Preece et al.
Journal of chromatography, 573(2), 227-234 (1992-01-17)
Plasma and liver levels of hydrazine were determined at 10, 30, 90 and 270 min in rats given 0.09, 0.27, 0.84 and 2.53 mmol of hydrazine per kg body weight orally by capillary gas chromatography-mass spectrometry of its pentafluorobenzaldehyde adduct
N E Preece et al.
Biochemical pharmacology, 41(9), 1319-1324 (1991-05-01)
15N-NMR has been used to study the metabolism of hydrazine in rats in vivo. Single doses of [15N2]hydrazine (2.0 mmol/kg: 98.6% g atom) were administered to rats and urine collected for 24 hr over ice. A number of metabolites were
D J Fort et al.
Teratogenesis, carcinogenesis, and mutagenesis, 10(6), 463-476 (1990-01-01)
The developmental toxicity of isoniazid (INH) and the metabolites acetylhydrazide (AH) and isonicotinic acid (INA) were examined with the frog embryo teratogenesis assay-Xenopus (FETAX). Late Xenopus laevis blastulae were exposed to INH, AH, and INA for 96 h in two
Shahrzad Tafazoli et al.
Toxicology and applied pharmacology, 229(1), 94-101 (2008-02-26)
Isoniazid is an anti-tuberculosis drug that can cause hepatotoxicity in 20% of patients that is usually associated with an inflammatory response. Hepatocytes when exposed to non-toxic levels of H2O2, to simulate H2O2 formation by inflammatory cells, became twice as sensitive
B K Sinha
Biochimica et biophysica acta, 924(2), 261-269 (1987-05-19)
Spin-trapping techniques and electron spin resonance spectroscopy have been used to study bioactivations of hydrazine and its derivatives by isolated perfused rat livers. Using phenylbutylnitrone (PBN) as the stable spin trap, it was found that the liver perfusion of hydrazine
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