798959

cis-2-Bromovinylboronic acid MIDA ester

90%

• Synonym(e): MIDA006
• Empirische Formel (Hill-System): C₇H₉BBrNO₄
• CAS-Nummer: 1105069-27-9
• Molekulargewicht: 261.87
• UNSPSC-Code: 12352103
• NACRES: NA.22

Eigenschaften

• Assay: 90%
• Form: solid
• mp (Schmelzpunkt): 153-159 °C (Decomp.)
• Lagertemp.: −20°C
• SMILES String: CN1CC(=O)OB(OC(=O)C1)\C=C/Br
• InChI: 1S/C7H9BBrNO4/c1-10-4-6(11)13-8(2-3-9)14-7(12)5-10/h2-3H,4-5H2,1H3/b3-2-
• InChIKey: ALXOFLXCBIRRRC-IHWYPQMZSA-N

Beschreibung

Anwendung

The (Z)-(2-Bromovinyl)-MIDA boronate is a unique building block for the incorporation of cis-olefin for small molecule synthesis. Burke and coworkers have displayed the extreme versatility of this building block in the construction of polyene-containing natural product motifs.

Sonstige Hinweise

Synthesis of most polyene natural product motifs using just 12 building blocks and one coupling reaction

(Z)-(2-Bromovinyl)-MIDA boronate: a readily accessible and highly versatile building block for small molecule synthesis

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable