793434

4-Tolyl-α-MIDA-boryl aldehyde

• Synonym(e): (6-Methyl-4,8-dioxo-1,3,6,2-dioxazaborocan-2-yl)(4-methylphenyl)acetaldehyde
• Empirische Formel (Hill-System): C₁₄H₁₆BNO₅
• CAS-Nummer: 1329422-56-1
• Molekulargewicht: 289.09
• MDL-Nummer: MFCD27665011
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 329768076
• NACRES: NA.22

Eigenschaften

• Form: solid
• mp (Schmelzpunkt): 135-142 °C
• Funktionelle Gruppe: aldehyde
• Lagertemp.: 2-8°C
• SMILES String: O=C1OB(C(C2=CC=C(C)C=C2)C([H])=O)OC(CN(C)C1)=O
• InChI: 1S/C14H16BNO5/c1-10-3-5-11(6-4-10)12(9-17)15-20-13(18)7-16(2)8-14(19)21-15/h3-6,9,12H,7-8H2,1-2H3
• InChIKey: DCVSWHVQPHHNBM-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

4-Tolyl-α-MIDA-boryl aldehyde is a-boryl aldehyde derivative. It can be synthesized from oxiranyl MIDA boronates, via rearrangement.[1]

Anwendung

This boronic acid derivative is in a series of the first known stable α-boryl aldehyde species. Through the employment of the MIDA-protected boronic ester, this building block has been shown as a precursor to the synthesis of unnatural amino acids.

Sonstige Hinweise

Amphoteric Alpha-Boryl Aldehydes

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable