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Merck

735817

Sigma-Aldrich

Polypyrrol-block-poly(caprolacton)

0.3-0.7 wt. % (dispersion in nitromethane), contains p-toluenesulfonate as dopant

Synonym(e):

Biotron PP-NM, PCL-block-PPy

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About This Item

UNSPSC-Code:
12352103
NACRES:
NA.23

Form

liquid (dispersion)

Enthält

p-toluenesulfonate as dopant

Zusammensetzung

Biotron PP polymer, 0.3-0.7 wt. %
ethanol, 4-8 wt. %
nitromethane, 90-95 wt. %

Konzentration

0.3-0.7 wt. % (dispersion in nitromethane)

Leitfähigkeit

10-40 S/cm (bulk)

Allgemeine Beschreibung

Sheet resistance, spin cast thin films: 10,000-50,000 Ohms/sq

Average transmittance: 70-90%

Biodegradble conducting polymer for bomedical applications. PCL diol blocks have average molecular weight 2000 and PPy block have an average molecular weight of 4000 with a 25% doping level. Good biocompatibility with expected weight loss of 40% at 200 days in pH=7 buffer.

Anwendung

Thin films can be prepared by spin casting the nitromethane dispersion at 1000 rpm. Thicker and more conducting films can be prepared by air spraying the dispersion on a substrate. Sprayed films can be dried at 30-40°C, then pressed between two polished dye plates at 1000-10,000 psi to increase film density, strength and scratch resistance.

Leistungsmerkmale und Vorteile

The block copolymer structure renders the conducting polymer polypyrrole dispersible in organic solvents and biodegradable.

Vorsicht

Store this product at room temperature (do not refrigerate or freeze). Severe settling and separation will normally occur. Agitate, sonicate, and filter prior to use. A plug of glass wool in a pipette can be used for easy filtration. The shelf life of this product will vary depending on how it is stored and handled. Product should be discarded if heavy aggregation occurs, or if sonication / filtering are inadequate to produce a good casting solution. When spray coating is used, the user should take every precaution necessarily to prevent exposure to solvent vapors from this product

Sonstige Hinweise

Will settle over time. Must be sonicated before use

Rechtliche Hinweise

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Repr. 2

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

66.9 °F

Flammpunkt (°C)

19.4 °C


Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Chemical Synthesis and Morphology of b?Naphthalene Sulfonic Acid-Doped Polypyrrole Micro/Nanotube.
Akinyeye R, et al.
Fullerenes, Nanotubes, and Carbon Nanostructures, 14 (2006)
Soluble conducting polypyrrole doped with DBSA?CSA mixed acid
Shen Y and Wan M
Journal of Applied Polymer Science, 68(8), 1277-1284 (1998)

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