733210

Tetrakis(dimethylsulfoxid)dichlorruthenium(II)

96%

• Synonym(e): Dichlorotetrakis(dimethyl sulfoxide)ruthenium
• Empirische Formel (Hill-System): C₈H₂₄Cl₂O₄RuS₄
• CAS-Nummer: 89395-66-4
• Molekulargewicht: 484.51
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329764798
• NACRES: NA.22

Eigenschaften

• Assay: 96%
• Form: solid
• Eignung der Reaktion: core: ruthenium; reagent type: catalyst
• mp (Schmelzpunkt): 192-198 °C
• SMILES String: O=S(C)C.O=S(C)C.Cl[Ru](Cl)O=S(C)C.O=S(C)C
• InChI: 1S/4C2H6OS.2ClH.Ru/c4*1-4(2)3;;;/h4*1-2H3;2*1H;/q;;;;;;+2/p-2
• InChIKey: UMJDEUKQHKMAOI-UHFFFAOYSA-L

Beschreibung

Allgemeine Beschreibung

Tetrakis(dimethylsulfoxide)dichlororuthenium(II), [RuCl₂(dmso)₄] is an organoruthenium compound. It is used as a homogeneous catalyst in organic synthesis.

Tetrakis(dimethylsulfoxide)dichlororuthenium(II) (Ru(DMSO)4Cl2) is a coordination complex generally used as a catalyst in various reactions. In addition, it is also used as a precursor in the synthesis of other ruthenium complexes.

Anwendung

RuCl₂(dmso)₄ can be used as a catalyst for:

• The β-alkylation of secondary alcohols via hydrogen auto-transfer process.
• The oxidation of thioethers (S) to sulfoxides by N-methylmorpholine N-oxide (NMO).

Tetrakis(dimethylsulfoxide)dichlororuthenium(II) can be used as a precursor in the synthesis of Ru(II)-MEPE (metallo-supramolecular polyelectrolytes) complex, which is used to prepare electrochromic organic-metallic hybrid polymers.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable