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6-Fluor-2H-1,4-benzoxazin-3(4H)-on
97%
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About This Item
Empirische Formel (Hill-System):
C8H6FNO2
CAS-Nummer:
Molekulargewicht:
167.14
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
Assay
97%
Form
solid
mp (Schmelzpunkt)
207-211 °C (lit.)
Funktionelle Gruppe
fluoro
SMILES String
Fc1ccc2OCC(=O)Nc2c1
InChI
1S/C8H6FNO2/c9-5-1-2-7-6(3-5)10-8(11)4-12-7/h1-3H,4H2,(H,10,11)
InChIKey
ZKNRUFWEZPGGQP-UHFFFAOYSA-N
Allgemeine Beschreibung
Due to the presence of halogen (F) at C-6 position in 6-fluoro-2H-1,4-benzoxazin-3(4H)-one (in active form), it exhibits phytotoxic activity.
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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H B Dunford
Redox report : communications in free radical research, 5(4), 169-171 (2000-09-20)
The first complete mechanistic analysis of halide ion oxidation by a peroxidase was that of iodide oxidation by horseradish peroxidase. It was shown conclusively that a two-electron oxidation of iodide by compound I was occurring. This implied that oxygen atom
Francisco A Macías et al.
Journal of agricultural and food chemistry, 54(26), 9843-9851 (2006-12-21)
The utility of benzoxazinones and some of their synthetic derivatives in the search for new leads for herbicide model development has been widely discussed. As the benzoxazinone skeleton contains three different potential areas for functionalization (C-2, N-4, and aromatic protons
Catalytic hydrogenation of sulfur-containing nitrobenzene over Pd/C catalysts: In situ sulfidation of Pd/C for the preparation of Pd x S y catalysts.
Zhang Q, et al.
Applied Catalysis A: General, 497, 17-21 (2015)
Photoelectrochemical reduction of meta-halonitrobenzenes and related species.
Robert AW and George WJ.
J. Chem. Soc. Perkin Trans. II, 8, 1673-1677 (1995)
The proximate coupling constant, 5 J (H, CH3), and the torsional mobility of the thiomethyl group in some thioanisole derivatives.
Schaefer T, et al.
Canadian Journal of Chemistry, 69(4), 620-624 (1991)
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