497924

6-Cyanohexylzinkbromid -Lösung

0.5 M in THF

• Lineare Formel: NC(CH₂)₆ZnBr
• CAS-Nummer: 312624-28-5
• Molekulargewicht: 255.47
• MDL-Nummer: MFCD01316997
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24873155
• NACRES: NA.22

Eigenschaften

• Konzentration: 0.5 M in THF
• Dichte: 0.944 g/mL at 25 °C
• Lagertemp.: 2-8°C
• SMILES String: Br[Zn]CCCCCCC#N
• InChI: 1S/C7H12N.BrH.Zn/c1-2-3-4-5-6-7-8;;/h1-6H2;1H;/q;;+1/p-1
• InChIKey: YDXOVAJDARDUOR-UHFFFAOYSA-M

Beschreibung

Anwendung

6-Cyanohexylzinc bromide is an organozinc compound, which can be used as a reactant in palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bonds by coupling with organic halides or triflates.
It can also be used as a reactant to synthesize:

• Cyanohexyl substituted aryl derivatives by palladium catalyzed coupling reaction with aryl bromides.
• Methyl 5-(6-cyanohexyl)-3-methylfuran-2-carboxylate, a key intermediate which is used in the preparation of cyclic furfuryl ether via Wittig rearrangement.

Rechtliche Hinweise

Product of Rieke^® Metals, Inc.

Rieke is a registered trademark of Rieke Metals, Inc.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS07
• Signalwort: Danger
• H-Sätze: H225,H319,H335,H336,H351
• P-Sätze: P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Zielorgane: Central nervous system, Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014,EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 1.4 °F - closed cup
• Flammpunkt (°C): -17 °C - closed cup