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Merck

316954

Sigma-Aldrich

Ammoniumperrhenat

≥99%

Synonym(e):

Metaperrhenic acid ammonium salt, Rhenium standard solution

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5 G
CHF 211.00
25 G
CHF 541.00

About This Item

Lineare Formel:
NH4ReO4
CAS-Nummer:
Molekulargewicht:
268.24
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.23

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Qualitätsniveau

Assay

≥99%

Form

powder or crystals

Eignung der Reaktion

reagent type: catalyst
core: rhenium

Dichte

3.97 g/mL at 25 °C (lit.)

SMILES String

N.O[Re](=O)(=O)=O

InChI

1S/H3N.H2O.3O.Re/h1H3;1H2;;;;/q;;;;;+1/p-1

InChIKey

XPSXHXWHJAIQJR-UHFFFAOYSA-M

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Allgemeine Beschreibung

Ammonium perrhenate is a white crystalline solid soluble in ethanol and water. It is a weak oxidizer and widely used as a Re precursor in nanomaterial synthesis and Re-based catalyst preparation.

Anwendung

Ammonium perrhenate used:
  • As a rhenium source to prepare Re nanoparticles for catalytic decomposition of ammonium perchlorate.
  • To synthesize ReS2 through a direct sulfidation reaction, for the fabrication of field effect transistors (FETs), digital logic devices, humidity sensors, and rechargeable supercapacitors.
  • As a precursor to prepare the heterogeneous catalysts for organic transformations.
  • An excellent precursor for the fabrication of ReOx/TiO2 recyclable solidcatalyst for deoxydehydration. For at least six runs in a row, the catalyst demonstrated catalyticactivity, selectivity, and stability without deactivation.

Lagerklassenschlüssel

13 - Non Combustible Solids

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Xuezeng Tian et al.
Nature materials, 19(8), 867-873 (2020-03-11)
The electronic, optical and chemical properties of two-dimensional transition metal dichalcogenides strongly depend on their three-dimensional atomic structure and crystal defects. Using Re-doped MoS2 as a model system, here we present scanning atomic electron tomography as a method to determine
Zixuan Wang et al.
Small (Weinheim an der Bergstrasse, Germany), 16(20), e2000852-e2000852 (2020-04-24)
Tuning bandgap and phases in the ternary 2D transition metal dichalcogenides (TMDs) alloys has opened up unexpected opportunities to engineer optoelectronic properties and explore potential applications. In this work, a salt-assisted chemical deposition vapor (CVD) growth strategy is reported for
Perez-Lourido, P. et al.
Inorganic Chemistry, 38, 1511-1511 (1999)
Jeffrey G Linger et al.
Proceedings of the National Academy of Sciences of the United States of America, 111(33), 12013-12018 (2014-08-06)
Lignin is an energy-dense, heterogeneous polymer comprised of phenylpropanoid monomers used by plants for structure, water transport, and defense, and it is the second most abundant biopolymer on Earth after cellulose. In production of fuels and chemicals from biomass, lignin
Jong Kwon Choe et al.
Environmental science & technology, 44(12), 4716-4721 (2010-05-21)
Recent work demonstrates reduction of aqueous perchlorate by hydrogen at ambient temperatures and pressures using a novel rhenium-palladium bimetal catalyst immobilized on activated carbon (Re/Pd-AC). This study examines the influence of Re speciation on catalyst activity and stability. Rates of

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