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Merck

307696

Sigma-Aldrich

Cobalt(II)-phthalocyanin

β-form, Dye content 97 %

Synonym(e):

PcCo, Phthalocyanin, Phthalocyanin Cobalt(II)-salz

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About This Item

Empirische Formel (Hill-System):
C32H16CoN8
CAS-Nummer:
Molekulargewicht:
571.46
Beilstein:
4121847
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

Qualitätsniveau

Form

powder

Zusammensetzung

Dye content, 97%

SMILES String

[Co]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.Co/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChIKey

MPMSMUBQXQALQI-UHFFFAOYSA-N

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Allgemeine Beschreibung

Cobalt(II) phthalocyanine (CoPC )is a metallopthalocyanine.

Anwendung

Self assembled molecules of CoPC were deposited on epitaxial graphene. CoPC may be used to develop carbon black based electrocatalysts. CoPC modified carbon paste may be used as indicators for electrocatalytic amperometric measurements. ZnO impregnated with CoPC may be used as a sensitizer to determine the photodegradation of cyanide in aqueous suspension. CoPC catalysed aerobic regenerations of aldehydes and ketones have been investigated. CoPC may also be used as an end capping agent of a hyperbranched poly(aryl ether ketone) to be used for oxidative decomposition of 2,4,6,-trichlorophenol.

Piktogramme

Health hazard

Signalwort

Warning

H-Sätze

Gefahreneinstufungen

Carc. 2

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


Analysenzertifikate (COA)

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Die Dokumentenbibliothek aufrufen

Tatsuhiko Honda et al.
Journal of the American Chemical Society, 134(9), 4196-4206 (2012-02-04)
Proton-coupled electron-transfer reduction of dioxygen (O(2)) to afford hydrogen peroxide (H(2)O(2)) was investigated by using ferrocene derivatives as reductants and saddle-distorted (α-octaphenylphthalocyaninato)cobalt(II) (Co(II)(Ph(8)Pc)) as a catalyst under acidic conditions. The selective two-electron reduction of O(2) by dimethylferrocene (Me(2)Fc) and decamethylferrocene
The use of copper and cobalt phthalocyanines as electrocatalysts for the oxygen reduction reaction in acid medium.
Reis RM, et al.
Electrochimica Acta, 139, 1-6 (2014)
R M Pemberton et al.
Biosensors & bioelectronics, 42, 668-677 (2012-12-26)
A water-based carbon screen-printing ink formulation, containing the redox mediator cobalt phthalocyanine (CoPC) and the enzyme glucose oxidase (GOx), was investigated for its suitability to fabricate glucose microbiosensors in a 96-well microplate format: (1) the biosensor ink was dip-coated onto
Cobalt(II) phthalocyanine catalyzed aerobic regeneration of carbonyl compounds from the corresponding oximes in 1-butyl-3-methylimidazolium bromide
Shaabani A, et al.
Applied Catalysis A: General, 371(1-2), 148-152 (2009)
A I Medvedev et al.
Tsitologiia, 54(5), 417-420 (2012-07-26)
High-molecular-weight DNA fragments are the markers of the early stage of apoptosis induced in eukaryotic cells by cytotoxins of different nature. The dynamics of the development of large-scale DNA fragmentation in K-562 leukemia cells by the action of the antitumor

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