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Merck

277827

Sigma-Aldrich

4-Methylvaleriansäure

99%

Synonym(e):

4-Methylpentansäure, Isocapronsäure

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5 G
CHF 33.00
25 G
CHF 99.70

About This Item

Lineare Formel:
(CH3)2CHCH2CH2CO2H
CAS-Nummer:
Molekulargewicht:
116.16
Beilstein:
1741912
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22

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Qualitätsniveau

Assay

99%

Form

liquid

Brechungsindex

n20/D 1.414 (lit.)

bp

199-201 °C (lit.)

Dichte

0.923 g/mL at 25 °C (lit.)

Funktionelle Gruppe

carboxylic acid

SMILES String

CC(C)CCC(O)=O

InChI

1S/C6H12O2/c1-5(2)3-4-6(7)8/h5H,3-4H2,1-2H3,(H,7,8)

InChIKey

FGKJLKRYENPLQH-UHFFFAOYSA-N

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Allgemeine Beschreibung

Conductimetric detection of 4-methylvaleric acid on unfunctionized polymethacrylate resin (TSKgel G3000PWXL) columns has been reported[1].

Anwendung

4-Methylvaleric acid has been used in asymmetric synthesis of (4S)-4-isopropyl-3-[(2′S)-2′,4′-dimethyl-valeryl)]-2-oxazolidinone[2].

Piktogramme

Corrosion

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Eye Dam. 1 - Skin Corr. 1C

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

206.6 °F - closed cup

Flammpunkt (°C)

97 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Die Dokumentenbibliothek aufrufen

Progress towards the total synthesis of callipeltin A. Asymmetric synthesis of (2R, 3R, 4S)-3-hydroxy-2, 4, 6-trimethylheptanoic acid.
Guerlavais V, et al.
Tetrahedron Asymmetry, 13(7), 675-680 (2002)
Kazutoku Ohta et al.
Journal of chromatography. A, 1039(1-2), 171-177 (2004-07-15)
The application of unfunctionized polymethacrylate resin (TSKgel G3000PWXL) as a stationary phase in liquid chromatography with conductimetric detection for C1-C7 aliphatic monocarboxylic acids (formic acid, acetic acid, propionic acid, butyric acid, isovaleric acid, valeric acid, 3,3-dimethylbutyric acid, 4-methylvaleric acid, hexanoic
R Gunasegaram et al.
Acta endocrinologica, 102(2), 288-291 (1983-02-01)
With a view to establish the hitherto undescribed role of cholesterol in foetal-membranous steroidogenesis, homogenates of term chorion pars reflexa and amnion pars reflexa and pars placentaris collected from 6 women after spontaneous labour at term (38 to 41 weeks
F Pepersack et al.
Journal of clinical pathology, 36(11), 1233-1236 (1983-11-01)
In order to determine if gas-liquid chromatography (GLC) on concentrated stool extracts could be substituted to cell culture assay for cytotoxicity, we prospectively studied 154 diarrhoeal stools submitted for detection of Clostridium difficile toxin. Isocaproic-positive samples were cultured on egg
G E Mortimore et al.
The Journal of biological chemistry, 262(34), 16322-16327 (1987-12-05)
Previous studies with livers from fed rats perfused in the single-pass mode have shown that regulatory amino acids (Leu, Tyr, Gln, Pro, Met, His, and Trp) as a group as well as leucine alone inhibit deprivation-induced protein degradation optimally at

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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