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4,5-Dimethylthiazol
97%
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About This Item
Empirische Formel (Hill-System):
C5H7NS
CAS-Nummer:
Molekulargewicht:
113.18
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Assay
97%
Form
powder
Brechungsindex
n20/D 1.521 (lit.)
bp
158 °C/742 mmHg (lit.)
Dichte
1.07 g/mL at 25 °C (lit.)
SMILES String
Cc1ncsc1C
InChI
1S/C5H7NS/c1-4-5(2)7-3-6-4/h3H,1-2H3
InChIKey
UWSONZCNXUSTKW-UHFFFAOYSA-N
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Allgemeine Beschreibung
Radical bromination of 4,5-dimethylthiazole using N-bromosuccinimide in the presence of 2,2′-azobisisobutyronitrile yields mono-, tri- and tetrabromo compounds.
Anwendung
4,5-Dimethylthiazole was used in the preparation of 4-(bromomethyl)-5-(dibromomethyl)thiazole.
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
3 - Flammable liquids
WGK
WGK 3
Flammpunkt (°F)
123.8 °F - closed cup
Flammpunkt (°C)
51 °C - closed cup
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Mouaffak Al Hariri et al.
The Journal of organic chemistry, 62(2), 405-410 (1997-01-24)
4-(Bromomethyl)-5-(dibromomethyl)thiazole (1) was prepared in good yields by bromination of 4,5-dimethylthiazole with 3.3 equiv of NBS in the presence of AIBN. Treatment of 1 with sodium iodide led to a thiazole o-quinodimethane 2 which was trapped in situ with dienophiles
Selective Bromination of 4, 5-Dimethylthiazole with N-Bromosuccinimide.
Al Hariri M, et al.
European Journal of Organic Chemistry, 1998(4), 593-594 (1998)
Le Wu et al.
Journal of molecular neuroscience : MN, 56(4), 848-857 (2015-02-24)
Lipoxin A4 (LXA4), a potent antioxidant and anti-inflammation mediator, protects brains against cerebral ischemia/reperfusion (I/R) injury in vivo. However, few reports concern its function on astrocytes during cerebral I/R injury. The pathogenesis of cerebral I/R injury involves oxidative stress caused
João G Marques et al.
Pharmaceutical research, 31(9), 2516-2528 (2014-03-14)
Cancer multi-drug resistance is a major issue associated with current anti-tumoral therapeutics. In this work, Crizotinib an anti-tumoral drug approved for the treatment of non-small lung cancer in humans, and Sildenafil (Viagra(®)), were loaded into micellar carriers to evaluate the
Rui-Nan Zhang et al.
Hepatitis monthly, 15(5), e27909-e27909 (2015-06-06)
Chronic Hepatitis B (CHB) infection is common in patients with Non-Alcoholic Fatty Liver Disease (NAFLD). The replication level of Hepatitis B Virus (HBV) was inversely correlated with hepatic steatosis. Toll-Like Receptor (TLR) 4-mediated innate immunity plays a pivotal role in
Unser Team von Wissenschaftlern verfügt über Erfahrung in allen Forschungsbereichen einschließlich Life Science, Materialwissenschaften, chemischer Synthese, Chromatographie, Analytik und vielen mehr..
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