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Merck

204625

Sigma-Aldrich

Thallium(I)-sulfat

99.99% trace metals basis

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About This Item

Lineare Formel:
Tl2SO4
CAS-Nummer:
Molekulargewicht:
504.83
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12161600
eCl@ss:
38120904
PubChem Substanz-ID:
NACRES:
NA.22

Qualitätsniveau

Assay

99.99% trace metals basis

Form

solid

Eignung der Reaktion

core: thallium
reagent type: catalyst

mp (Schmelzpunkt)

632 °C (lit.)

Dichte

6.77 g/mL at 25 °C (lit.)

SMILES String

[Tl+].[Tl+].[O-]S([O-])(=O)=O

InChI

1S/H2O4S.2Tl/c1-5(2,3)4;;/h(H2,1,2,3,4);;/q;2*+1/p-2

InChIKey

YTQVHRVITVLIRD-UHFFFAOYSA-L

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Allgemeine Beschreibung

Thallium(I) sulfate is mainly used in organic synthesis as an oxidizing agent. It can facilitate the oxidation of various organic compounds, such as alcohols, to corresponding aldehydes or ketones. This reaction is commonly known as the Reformatsky reaction.1 Additionally, thallium sulfate is employed in the preparation of thallium salts for use in analytical chemistry and research applications. It is also utilized in the production of luminous paints, photoelectric cells, and low-melting glasses.

Anwendung

Thallium(I)sulfate is also utilized in:

  • the synthesis of alkylated cyclopentadienes and 7-substitutedbicyclo[2.2.1]heptane derivatives
  • inthe preparation of thallium borate species such as TlBPH43

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 2 - Skin Irrit. 2 - STOT RE 1 Oral

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Analysenzertifikate (COA)

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Methoxymethylation of thallous cyclopentadienide. Simplified preparation of a key intermediate for the synthesis of prostaglandins
Elias J. Corey, Urs Koelliker, and Jorg Neuffer
Journal of the American Chemical Society, 93(6), 1489?1490-1489?1490 (1971)
L Migliore et al.
Environmental and molecular mutagenesis, 34(4), 279-284 (2000-01-05)
The capability of some metal compounds for inducing micronuclei (MN) in human lymphocytes was studied. In this investigation, Al (III), Cd (II), Hg (II), Sb (V), Te (VI), and Tl (I) salts were considered. The FISH (fluorescence in situ hybridization)
D Appenroth et al.
Toxicology letters, 122(3), 255-265 (2001-08-08)
Antioxidants of the vitamin E family have protective effects against metal toxicity. We examined the protective effect of racemic LLU-alpha [2,7,8-trimethyl-2-(carboxyethyl)-6-hydroxychroman] a metabolite of gamma-tocopherol, in comparison to the effect of alpha- and gamma-tocopherol in rats treated with sodium dichromate
J T Kielstein et al.
Kidney & blood pressure research, 27(3), 197-199 (2004-07-17)
Guided by the idea of providing a stable electrolyte composition of the dialysate, the late Bernd Tersteegen designed a machine ingeniously combining the advantages of a closed tank hemodialysis system with the efficacy and bacteriological safety of a single-pass system.
Changes in adenosine triphosphate (ATP) concentration and its activity in murine tissue after thallium administration.
M Yoshida et al.
Bulletin of environmental contamination and toxicology, 59(2), 268-273 (1997-08-01)

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