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Sigma-Aldrich

2,4,6-Tribromphenol

99%

Synonym(e):

1,3,5-Tribromo-2-hydroxybenzene, Bromol

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About This Item

Lineare Formel:
Br3C6H2OH
CAS-Nummer:
118-79-6
Molekulargewicht:
330.80
Beilstein:
776920
EG-Nummer:
204-278-6
MDL-Nummer:
MFCD00002150
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24848344
NACRES:
NA.22

Dampfdichte

11.4 (vs air)

Assay

99%

bp

282-290 °C/746 mmHg (lit.)

mp (Schmelzpunkt)

90-94 °C (lit.)

Löslichkeit

water: soluble 0.007g/100ml at 25 °C
chloroform: soluble
diethyl ether: soluble
ethanol: soluble
methanol: soluble
methylene chloride: soluble

SMILES String

Oc1c(Br)cc(Br)cc1Br

InChI

1S/C6H3Br3O/c7-3-1-4(8)6(10)5(9)2-3/h1-2,10H

InChIKey

BSWWXRFVMJHFBN-UHFFFAOYSA-N

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Allgemeine Beschreibung

2,4,6-Tribromophenol undergoes oxidative degradation catalyzed by SiO2-supported iron(III)-5,10,15,20-tetrakis(4-carboxyphenyl) porphyrin. It is degraded by Bacillus sp.GZT strain via reductive bromination as major degradation pathway. It is a widely used brominated flame retardant.

Anwendung

2,4,6-Tribromophenol was used in analysis of nonylphenol, nonylphenol monoethoxylate and octylphenol in sediment, water and fish tissue.

Piktogramme

Exclamation markEnvironment
GHS07,GHS09

Signalwort

Warning

Gefahreneinstufungen

Aquatic Acute 1 - Eye Irrit. 2 - Skin Sens. 1

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Analysenzertifikate (COA)

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Qianqian Zhu et al.
Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering, 48(13), 1593-1601 (2013-08-21)
Iron(III)-porphyrin complexes are generally regarded as green catalysts, since they mimic the catalytic center of cytochrome-P450 and widely used as green catalysts for degrading halogenated phenols in wastewater, such as landfill leachates. However, iron(III)-porphyrins are deactivated by self-oxidation in the
Estrogenic alkylphenols in fish tissues, sediments, and waters from the UK Tyne and Tees estuaries.
Lye CM, et al.
Environmental Science & Technology, 33(7), 1009-1014 (1999)
Taiki Futagami et al.
Applied and environmental microbiology, 75(21), 6905-6909 (2009-09-15)
Halogenated organic compounds serve as terminal electron acceptors for anaerobic respiration in a diverse range of microorganisms. Here, we report on the widespread distribution and diversity of reductive dehalogenase homologous (rdhA) genes in marine subsurface sediments. A total of 32
Natsuko Kajiwara et al.
Journal of hazardous materials, 192(3), 1250-1259 (2011-07-26)
The concentrations of traditional brominated flame retardants (BFRs) and organophosphate flame retardants (OPFRs) in new consumer products, including electronic equipment, curtains, wallpaper, and building materials, on the Japanese market in 2008 were investigated. Although some components of the electronic equipment
C Pizarro et al.
Journal of chromatography. A, 1217(49), 7630-7637 (2010-11-03)
A dispersive liquid-liquid microextraction (DLLME) method has been optimised for simultaneously extracting 2,4,6-trichloranisole (TCA), 2,3,4,6-tetrachloroanisole (TeCA), 2,4,6-tribromoanisole (TBA), pentachloroanisole (PCA), 2,4,6-trichlorophenol (TCP), 2,3,4,6-tetrachlorophenol (TeCP), 2,4,6-tribromophenol (TBP) and pentachlorophenol (PCP) from wine. The haloanisoles and halophenols were automatically determined using a
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