105457

2,4-Dinitro-benzolsulfenylchlorid

96%

• Synonym(e): 2,4-Dinitrophenylsulfenylchlorid, Kharasch Reagens
• Lineare Formel: (O₂N)₂C₆H₃SCl
• CAS-Nummer: 528-76-7
• Molekulargewicht: 234.62
• Beilstein: 405600
• EG-Nummer: 208-441-2
• MDL-Nummer: MFCD00007129
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24846698
• NACRES: NA.22

Eigenschaften

• Assay: 96%
• mp (Schmelzpunkt): 94-97 °C (lit.)
• Löslichkeit: benzene: soluble; diethyl ether: soluble; ethylene chloride: soluble; glacial acetic acid: soluble; methylene chloride: soluble; trichloroethylene: soluble; xylene: soluble
• Lagertemp.: 2-8°C
• SMILES String: [O-][N+](=O)c1ccc(SCl)c(c1)[N+]([O-])=O
• InChI: 1S/C6H3ClN2O4S/c7-14-6-2-1-4(8(10)11)3-5(6)9(12)13/h1-3H
• InChIKey: GPXDNWQSQHFKRB-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

2,4-Dinitrobenzenesulfenyl chloride undergoes addition reactions with transannularly substituted cycloalkenes and norbornenes. 2,4-Dinitrobenzenesulfenyl chloride can convert allylic alcohols to dienes by 1,4-elimination.

Anwendung

2,4-Dinitrobenzenesulfenyl chloride was used in preparation of chlorine and bromine biphenyls.

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Gefahreneinstufungen: Eye Dam. 1 - Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges