73341

Echinenone

≥95.0% (HPLC), solid

• Sinônimo(s): β,β-Caroten-4-one
• Fórmula empírica (Notação de Hill): C₄₀H₅₄O
• Número CAS: 432-68-8
• Peso molecular: 550.86
• Beilstein: 2030114
• Número CE: 207-083-4
• Número MDL: MFCD06656303
• Código UNSPSC: 12352202
• ID de substância PubChem: 329764812
• NACRES: NA.32

Propriedades

• Nome do produto: Echinenone, ≥95.0% (HPLC)
• Ensaio: ≥95.0% (HPLC)
• Formulário: solid
• λ: in hexane (with 2% dichloromethane)
• Absorção UV: λ: 459 nm±5 nm A_max
• temperatura de armazenamento: −20°C
• cadeia de caracteres SMILES: CC(/C=C/C1=C(C)C(CCC1(C)C)=O)=C\C=C\C(C)=C\C=C\C=C(C)\C=C\C=C(\C=C\C2=C(C)CCCC2(C)C)C
• InChI: 1S/C40H54O/c1-30(18-13-20-32(3)23-25-36-34(5)22-15-28-39(36,7)8)16-11-12-17-31(2)19-14-21-33(4)24-26-37-35(6)38(41)27-29-40(37,9)10/h11-14,16-21,23-26H,15,22,27-29H2,1-10H3/b12-11+,18-13+,19-14+,25-23+,26-24+,30-16+,31-17+,32-20+,33-21+
• chave InChI: QXNWZXMBUKUYMD-QQGJMDNJSA-N

Descrição

Descrição geral

Echinenone is a carotenoid with a conjugated carbonyl group.[1] Echinenone (4-keto-β-carotene) is a monoketo compound, is an intermediate between β-carotene and canthaxanthin in animals.[2] It is one of the major carotenoids of Anabaena sp.,[3] and also present in Micrococcus roseus.[2] It is located in the thylakoid membrane of Anabaena. The conversion of β-carotene to echinenone is catalysed by CrtO, a β-carotene ketolase.[3]

Aplicação

Echinenone may be used as an external standard for the extraction of carotenoid from plasma samples.[4] It may also been used as an internal standard, added to samples for extraction and quantification.[5][6]

Ações bioquímicas/fisiológicas

Echinenone binds to glocobacter rhodopsin and functions as a light harvesting antenna in Gloeobacter violaceous.[7]

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable