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Supelco

Nickel(II) sulfate hexahydrate

≥99.99% trace metals basis

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About This Item

Fórmula linear:
NiSO4 · 6H2O
Número CAS:
Peso molecular:
262.85
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.55

grau

for inorganic trace analysis

Nível de qualidade

densidade de vapor

2.07 (vs air)

Ensaio

≥99.99% trace metals basis

forma

solid

Impurezas

≤0.002% N compounds
≤0.005% insolubles
<100 ppm total metallic impurities

traços de ânion

chloride (Cl-): ≤0.001%

traços de cátion

Ca: ≤0.005%
Co: ≤0.002%
Cu: ≤0.005%
Fe: ≤0.001%
K: ≤0.01%
Mg: ≤0.005%
Mn: ≤0.002%
Na: ≤0.05%

cadeia de caracteres SMILES

O.O.O.O.O.O.[Ni++].[O-]S([O-])(=O)=O

InChI

1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2

chave InChI

RRIWRJBSCGCBID-UHFFFAOYSA-L

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Descrição geral

Nickel (II) sulfate hexahydrate (NiSO4·6H2O), commonly called retgersite, is a naturally occurring enantiomorphic mineral. It crystallizes in the monoclinic space group C2/c. Crystal structure of its various polymorphic forms have been investigated. The chiral nickel sulfate hexahydrate has been reported to induce asymmetric autocatalysis. The thermal degradation behavior of nickel(II) sulfate(VI) hexahydrate in air and helium atmosphere has been studied using thermogravimetry (TG) and X-ray powder diffraction (XRD).

Aplicação


  • Improvement of ion chromatography with ultraviolet photometric detection and comparison with conductivity detection for the determination of serum cations.: This study explores advanced ion chromatography techniques for analyzing serum cations, where Nickel(II) sulfate hexahydrate may be used as a standard or in method development. The research compares ultraviolet photometric detection with conductivity detection, enhancing analytical methods for precise cation analysis in various samples, which can be crucial for environmental and clinical chemistry (Shintani H, 1985).

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Órgãos-alvo

Respiratory Tract

Código de classe de armazenamento

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


Certificados de análise (COA)

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Structure of monoclinic nickel (II) sulfate hexahydrate.
Gerkin RE and Reppart WJ.
Acta Crystallographica Section C, Crystal Structure Communications, 44(8), 1486-1488 (1988)
Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis.
Matsumoto A, et al.
New. J. Chem., 39(9), 6742-6745 (2015)
Polymorphism of nickel sulfate hexahydrate.
Angel RJ and Finger LW.
Acta Crystallographica Section C, Crystal Structure Communications, 44(11), 1869-1873 (1988)
Mechanism and kinetics of thermal decomposition of nickel (II) sulfate (VI) hexahydrate.
Tomaszewicz E and Kotfica M.
Journal of Thermal Analysis and Calorimetry, 77(1), 25-31 (2004)
Xiaohua Xu et al.
Particle and fibre toxicology, 9, 40-40 (2012-11-07)
It has been well recognized that toxicity of fine ambient air particulate matter (PM(2.5)) may depend on its chemical constituents, including components such as soluble metals that may theoretically exert distinctive effects. We have recently demonstrated an important effect of

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