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Documentos Principais

31173

Sigma-Aldrich

Ammonium cerium(IV) sulfate dihydrate

≥99%

Sinônimo(s):

Ceric ammonium sulfate, Cerium(IV) ammonium sulfate

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About This Item

Fórmula linear:
Ce(NH4)4(SO4)4 · 2H2O
Número CAS:
Peso molecular:
632.55
Número MDL:
Código UNSPSC:
12352300
ID de substância PubChem:

Ensaio

≥99%

adequação da reação

reagent type: catalyst
core: cerium

Impurezas

≤0.005% heavy metals (as Pb)
≤0.005% insoluble in acid

pf

130 °C (lit.)

traços de ânion

chloride (Cl-): ≤10 mg/kg
phosphate (PO43-): ≤50 mg/kg

traços de cátion

Fe: ≤50 mg/kg

cadeia de caracteres SMILES

N.N.N.N.O.O.[Ce+4].OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O

InChI

1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;4*1-5(2,3)4;;/h;4*1H3;4*(H2,1,2,3,4);2*1H2/q+4;;;;;;;;;;/p-4

chave InChI

VCNAMBGKEDPVGQ-UHFFFAOYSA-J

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Descrição geral

Ammonium cerium(IV) sulfate dihydrate (tetraammonium cerium(IV) sulphate dihydrate) is commonly employed as starting material for various organic syntheses. It is widely employed as oxidizing agent. Its thermal decomposition and thermal characteristics have been reported.[1]

Aplicação

Ammonium cerium(IV) sulfate may be used for the determination of urinary iodine by ammonium persulfate digestion on microplate (APDM) method[2] and colorimetric method.[3]
Ammonium cerium(IV) sulfate was used in thin-layer chromatography for the detection of anti-depreβant drugs in human blood and urine samples. [4]

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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N Sadeg et al.
Clinical chemistry, 43(3), 498-504 (1997-03-01)
We evaluated the clinical utility of an automated HPLC system (Remedi, Bio-Rad) for identification of drugs and metabolites in biological fluids. Serum or urine or both from 354 consecutive cases of poisoning were analyzed by the system and by a
T Ohashi et al.
Clinical chemistry, 46(4), 529-536 (2000-04-12)
Urinary iodine is a good biochemical marker for control of iodine deficiency disorders. Our aim was to develop and validate a simple, rapid, and quantitative method based on the Sandell-Kolthoff reaction, incorporating both the reaction and the digestion process into
Thermal behaviour of sulphato and nitrato complexes of cerium (IV).
Pokol G, et al.
J. Therm. Anal., 42(2-3), 343-359 (1994)
Fast colorimetric method for measuring urinary iodine.
Daniella Gnat et al.
Clinical chemistry, 49(1), 186-188 (2003-01-01)
Effect of high room temperature on urinary iodine assay.
N T Dung et al.
Clinical chemistry, 43(6 Pt 1), 1084-1085 (1997-06-01)

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