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Dichloro(p-cymene)ruthenium(II) dimer ChemBeads

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Sinônimo(s):

(p-Cymene)ruthenium(II) chloride dimer ChemBeads, Benzene-1-methyl-4-(1-methylethyl)-ruthenium complex ChemBeads

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About This Item

Fórmula empírica (Notação de Hill):
C20H28Cl4Ru2
Número CAS:
52462-29-0
Peso molecular:
612.39
Número MDL:
MFCD00064793
Código UNSPSC:
12352100

Formulário

solid

Nível de qualidade

100

composição

, 4-6 wt. % (loading)

adequação da reação

reagent type: catalyst

cadeia de caracteres SMILES

Cc1ccc(C(C)C)cc1.CC(C)c2ccc(C)cc2.Cl[Ru]3[ClH][Ru](Cl)[ClH]3

InChI

InChI=1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4

chave InChI

LAXRNWSASWOFOT-UHFFFAOYSA-J

Descrição geral

The ChemBeads product of the (p-Cymene)ruthenium(II) chloride dimer. Loaded at 5% wt. on glass beads for use in high-throughput expermentation (HTE).
Dichloro(p-cymene)ruthenium(II) dimer is commonly used as a ruthenium starting material, and has been used in:
- Bifunctional P-containing RuO2 catalysts prepared from surplus Ru coordination complexes applied to Zn/Air batteries.
- The synthesis of half-sandwich type platinum-group metal complexes of C-glucosaminyl azines.
- The C(sp2)-H bond functionalization along with concomitant (4+2) annulation of coumarin-3-carboxamide.
-The acceptor engineering of ruthenium metallocycles with high phototoxic indices for safer photodynamic therapy.

Características e benefícios

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

produto relacionado

Nº do produto
Descrição
Preços

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

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Certificados de análise (COA)

Lot/Batch Number
MKCW9260

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Chonglu Li et al.
Chemical science, 14(11), 2901-2909 (2023-03-21)
Although metallacycle-based photosensitizers have attracted increasing attention in biomedicine, their clinical application has been hindered by their inherent dark toxicity and unsatisfactory phototherapeutic efficiency. Herein, we employ a π-expansion strategy for ruthenium acceptors to develop a series of Ru(ii) metallacycles
Anindita Sarkar et al.
Organic & biomolecular chemistry, 21(27), 5567-5586 (2023-06-26)
Efficacious protocols have been established to synthesize a structurally privileged Π-extended coumarin-fused pyridone nucleus by activating the vinylic C(sp2)-H bond of coumarin-3-carboxamide under the influence of inexpensive Ru(II)-metal. Here an N-methoxy carboxamide entity has been exploited as the chelating fragment
Sebastián Lorca et al.
Nanomaterials (Basel, Switzerland), 13(1) (2023-01-09)
An innovative synthetic route that involves the thermal treatment of selected Ru co-ordination complexes was used to prepare RuO2-based materials with catalytic activity for oxygen reduction (ORR) and oxygen evolution (OER) reactions. Extensive characterization confirmed the presence of Ru metal
Bryan T Ingoglia et al.
Tetrahedron, 75(32), 4199-4211 (2020-01-04)
Over the past three decades, Pd-catalyzed cross-coupling reactions have become a mainstay of organic synthesis. In particular, catalysts derived from biaryl monophosphines have shown wide utility in forming C-N bonds under mild reaction conditions. This work summarizes a variety of
Noah P Tu et al.
Angewandte Chemie (International ed. in English), 58(24), 7987-7991 (2019-03-21)
Technologies that enable rapid screening of diverse reaction conditions are of critical importance to methodology development and reaction optimization, especially when molecules of high complexity and scarcity are involved. The lack of a general solid dispensing method for chemical reagents
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