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937053

N-XantPhos Pd G4 ChemBeads

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Sinônimo(s):

(SP-4-4)-[4-(Diphenylphosphino-κP)-6-(diphenylphosphino)-10H-phenoxazine](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium ChemBeads, 4,6-bis(diphenylphosphanyl)-10H-phenoxazine, [2′-(methylamino)-[1,1′-biphenyl]-2-yl]palladio methanesulfonate ChemBeads

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About This Item

Fórmula empírica (Notação de Hill):
C50H42N2O4P2PdS
Número CAS:
1878105-23-7
Peso molecular:
935.31
Número MDL:
MFCD30718059
Código UNSPSC:
12352100

Formulário

solid

Nível de qualidade

100

composição

, 4-6 wt. % (loading)

adequação da reação

reagent type: catalyst

cadeia de caracteres SMILES

[MsO][Pd]1C2=CC=CC=C2C3=CC=CC=C3N1C.C4(P(C5=CC=CC=C5)C6=CC=CC=C6)=C(OC(C(P(C7=CC=CC=C7)C8=CC=CC=C8)=CC=C9)=C9N%10)C%10=CC=C4

InChI

InChI=1S/C36H27NOP2.C13H12N.CH4O3S.Pd/c1-5-15-27(16-6-1)39(28-17-7-2-8-18-28)33-25-13-23-31-35(33)38-36-32(37-31)24-14-26-34(36)40(29-19-9-3-10-20-29)30-21-11-4-12-22-30;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h1-26,37H;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;-1;;+2/p-1

chave InChI

LQECMIPINHUTAN-UHFFFAOYSA-M

Descrição geral

The ChemBeads product of the N-XantPhos ligand combined with the Buchwald Fourth Generation Palladacycle. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents. Loaded at 5% wt. on glass beads for use in high-throughput expermentation (HTE).

Aplicação

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
For general uses, product is also available in powdered form (900455 )

Características e benefícios

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

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Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

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Certificados de análise (COA)

Lot/Batch Number
MKCW8335

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Palladium-Catalyzed C-H Arylation of ?,?-Unsaturated Imines: Catalyst-Controlled Synthesis of Enamine and Allylic Amine Derivatives.
Li M, et al.
Angewandte Chemie (International Edition in English), 55, 2825-2829 (2016)
Bryan T Ingoglia et al.
Tetrahedron, 75(32), 4199-4211 (2020-01-04)
Over the past three decades, Pd-catalyzed cross-coupling reactions have become a mainstay of organic synthesis. In particular, catalysts derived from biaryl monophosphines have shown wide utility in forming C-N bonds under mild reaction conditions. This work summarizes a variety of
Ana L Aguirre et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(51), 12981-12986 (2021-07-08)
High-throughput experimentation (HTE) methods are central to modern medicinal chemistry. While many HTE approaches to C-N and Csp2 -Csp2 bonds are available, options for Csp2 -Csp3 bonds are limited. We report here how the adaptation of nickel-catalyzed cross-electrophile coupling of
Noah P Tu et al.
Angewandte Chemie (International ed. in English), 58(24), 7987-7991 (2019-03-21)
Technologies that enable rapid screening of diverse reaction conditions are of critical importance to methodology development and reaction optimization, especially when molecules of high complexity and scarcity are involved. The lack of a general solid dispensing method for chemical reagents

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