132934

Aniline

ReagentPlus^®, 99%

• Sinônimo(s): Aminobenzene, Benzenamine
• Fórmula linear: C₆H₅NH₂
• Número CAS: 62-53-3
• Peso molecular: 93.13
• Beilstein: 605631
• Número CE: 200-539-3
• Número MDL: MFCD00007629
• Código UNSPSC: 12352100
• eCl@ss: 39030407
• ID de substância PubChem: 24848084
• NACRES: NA.21

Propriedades

• densidade de vapor: 3.22 (185 °C, vs air)
• Nível de qualidade: 200
• pressão de vapor: 0.7 mmHg ( 25 °C)
• linha de produto: ReagentPlus^®
• Ensaio: 99%
• forma: liquid
• temperatura de autoignição: 1139 °F
• Lim. expl.: 11 %
• índice de refração: n20/D 1.586 (lit.)
• pH: 8.8 (20 °C, 36 g/L)
• pb: 184 °C (lit.)
• pf: −6 °C (lit.)
• solubilidade: water: soluble
• densidade: 1.022 g/mL at 25 °C (lit.)
• cadeia de caracteres SMILES: Nc1ccccc1
• InChI: 1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2
• chave InChI: PAYRUJLWNCNPSJ-UHFFFAOYSA-N

Descrição

Descrição geral

Aniline is an aromatic amine. It is a key industrial intermediate, widely employed for the preparation of dyes, rubber, resins and polymers. Complete vibrational assignements of aniline and its deuterated forms (aniline-NHD and aniline-ND₂) have been reported.1 p-aminodiphenylamine (ADPA) has been reported to be formed as a major intermediate during the electropolymerizatrion of aniline. Its viscosity has been reported to be 3.1457cp at 30°C. Quantitative transformation of nitrobenzene to aniline has been carried out by employing functionalized plasmonic Au/TiO₂ photocatalyst along with a Ag co-catalyst. Aniline can be prepared from nitrobenzene, via hydrogenation in the presence of Cu, Ni, Pt, Pd and Au (catalyst). It can also be prepared by photocatalytic reduction of nitrobenzene in the presence of WO₃-Ag hybrid nanowires.

Aplicação

Aniline may be used in the preparation of azobenzene.

Ações bioquímicas/fisiológicas

The acute toxicity of aniline involves its activation in vivo to 4-hydroxyaniline and the formation of adducts with hemoglobin. In erythrocytes, this is associated with the release of iron and the accumulation of methemoglobin and the development of hemolytic anemia and inflammation of the spleen. Tumor formation is often observed in the spleen on prolonged administration.

propriedades físicas

Material darkens in storage to reddish-brown with no loss in purity.

Informações legais

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Informações de segurança

• Pictogramas: GHS06,GHS08,GHS05,GHS09
• Palavra indicadora: Danger
• Frases de perigo: H301 + H311 + H331,H317,H318,H341,H351,H372,H410
• Declarações de precaução: P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
• Classificações de perigo: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1
• Órgãos-alvo: Blood
• Código de classe de armazenamento: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 158.0 °F - closed cup
• Ponto de fulgor (°C): 70 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter