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Sigma-Aldrich

2,2′-Azobis(2-methylpropionitrile)

purum, ≥98.0% (GC)

Sinônimo(s):

α,α′-Azoisobutyronitrile, AIBN, Azobisisobutyronitrile, Free radical initiator

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About This Item

Fórmula linear:
(CH3)2C(CN)N=NC(CH3)2CN
Número CAS:
Peso molecular:
164.21
Beilstein:
1708400
Número CE:
Número MDL:
Código UNSPSC:
12162002
ID de substância PubChem:
NACRES:
NA.23

grau

purum

Nível de qualidade

Ensaio

≥98.0% (GC)

forma

solid

Impurezas

≤2% water

resíduo de ignição

≤0.1%

pf

102-104 °C (dec.) (lit.)

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

CC(C)(\N=N\C(C)(C)C#N)C#N

InChI

1S/C8H12N4/c1-7(2,5-9)11-12-8(3,4)6-10/h1-4H3/b12-11+

chave InChI

OZAIFHULBGXAKX-VAWYXSNFSA-N

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Descrição geral

Radical initiator

Aplicação

  • Polymer Chemistry: Analysis of polymer synthesis using AIBN under various conditions, with emphasis on thermal initiation properties (Suriyanarayanan & Nicholls, 2019).
  • Influence of cyclodextrin on the UCST-and LCST-behavior of poly (2-methacrylamido-caprolactam)-co-(N, N-dimethylacrylamide): Explores the role of AIBN in copolymerization processes influencing polymer properties relevant to material science applications (Burkhart & Ritter, 2014).
  • Preparation and characterization of polyaniline microcapsule loaded with 2, 2′‐azobis (2‐methylpropionitrile) initiator and its controlled release: Demonstrates innovative applications of AIBN in microencapsulation techniques, targeting enhanced performance in adhesive industries (Zhang et al., 2022).

Armazenamento e estabilidade

Warning: these products are subject to the Explosives Act and must be transported refrigerated - additional costs for transport will apply.

Outras notas

Sales restrictions may apply

Pictogramas

FlameExclamation mark

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Self-react. C

Perigos de suplementos

Código de classe de armazenamento

4.1A - Other explosive hazardous materials

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

122.0 °F

Ponto de fulgor (°C)

50 °C

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Wenwen Li et al.
Macromolecular rapid communications, 32(1), 74-81 (2011-03-25)
Amphiphilic star shaped polymers with poly(ethylene oxide) (PEO) arms and cross-linked hydrophobic core were synthesized in water via either conventional free radical polymerization (FRP) or atom transfer radical polymerization (ATRP) techniques using a simple "arm-first" method. In FRP, PEO based
Lianghui Liu et al.
Organic letters, 14(22), 5692-5695 (2012-10-31)
In the presence of a catalytic amount of radical initiator AIBN, primary amines are oxidatively coupled to imines and tertiary amines are cyanated to α-aminonitriles. These "metal-free" aerobic oxidative coupling reactions may find applications in a wide range of "green"
Mathieu Le Noir et al.
Journal of separation science, 32(9), 1471-1479 (2009-04-29)
Highly efficient removal of endocrine-disrupting compounds (EDCs) such as 17beta-estradiol (E2), 4-nonylphenol (NP) and atrazine from water was achieved using a novel macroporous adsorption medium. The medium consisted of a macroporous poly(vinyl alcohol) (PVA) cryogel with molecularly imprinted polymer (MIP)
K Shivaji Sharma et al.
Langmuir : the ACS journal of surfaces and colloids, 24(23), 13581-13590 (2008-11-05)
A novel class of nonionic amphipols (NAPols) designed to handle membrane proteins in aqueous solutions has been synthesized, and its solution properties have been examined. These were synthesized through free radical cotelomerization of glucose-based hydrophilic and amphiphilic monomers derived from
Idil Ipek Yilmaz et al.
Macromolecular rapid communications, 33(9), 856-862 (2012-04-21)
Polymers containing maleimide groups on their side chains have been synthesized by utilization of a novel styrenic monomer containing a masked-maleimide unit. AIBN initiated free radical polymerization and reverse addition-fragmentation chain transfer (RAFT) polymerization was utilized for synthesis of copolymers

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