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D79403

Sigma-Aldrich

Bicyclohexyl

99%

Sinônimo(s):

1,1′-Bi(cyclohexyl), BCH, Dicyclohexyl

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5 G
R$ 366,00
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R$ 366,00


Disponível para enviar em22 de abril de 2025Detalhes


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5 G
R$ 366,00
25 G
R$ 1.262,00
100 G
R$ 3.360,00

About This Item

Fórmula linear:
C6H11C6H11
Número CAS:
Peso molecular:
166.30
Beilstein:
1848266
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

R$ 366,00


Disponível para enviar em22 de abril de 2025Detalhes


Solicite uma grande encomenda

Nível de qualidade

Ensaio

99%

Formulário

liquid

temperatura de autoignição

473 °F

índice de refração

n20/D 1.478 (lit.)

p.e.

227 °C (lit.)

pf

3-4 °C (lit.)

densidade

0.864 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

C1CCC(CC1)C2CCCCC2

InChI

1S/C12H22/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h11-12H,1-10H2

chave InChI

WVIIMZNLDWSIRH-UHFFFAOYSA-N

Informações sobre genes

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Descrição geral

Bicyclohexyl, also known as Dicyclohexyl, is a non-volatile liquid with two cyclohexane rings joined by a single carbon-carbon bond. [1]

Aplicação

Bicyclohexyl can be used as a reactant:      
  • To synthesize 1-azido-1,1′-bi(cyclohexane) by Mn-catalyzed oxidative azidation method using nucleophilic NaN3 as an azide source.      
  • To prepare 1-fluoro-1,1′-bicyclohexyl using elemental fluorine.   
  • In the aliphatic Friedel-Crafts reaction to prepare novel bicyclohexyl based oxygenated building block via C-H activation with aluminum trichloride and acetyl chloride.

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Asp. Tox. 1 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

10 - Combustible liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

197.6 °F - closed cup

Ponto de fulgor (°C)

92 °C - closed cup

Equipamento de proteção individual

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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The selective installation of azide groups into C(sp3)-H bonds is a priority research topic in organic synthesis, particularly in pharmaceutical discovery and late-stage diversification. Herein, we demonstrate a generalized manganese-catalyzed oxidative azidation methodology of C(sp3)-H bonds using nucleophilic NaN3 as
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Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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