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B56501

Sigma-Aldrich

4-Bromoanisole

≥99.0%

Sinônimo(s):

1-Bromo-4-methoxybenzene

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About This Item

Fórmula linear:
BrC6H4OCH3
Número CAS:
104-92-7
Peso molecular:
187.03
Beilstein:
1237590
Número CE:
203-252-1
Número MDL:
MFCD00000097
Código UNSPSC:
12352100
ID de substância PubChem:
24891850
NACRES:
NA.22

Ensaio

≥99.0%

forma

liquid

índice de refração

n20/D 1.564 (lit.)

pb

223 °C (lit.)

pf

9-10 °C (lit.)

densidade

1.494 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

COc1ccc(Br)cc1

InChI

1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3

chave InChI

QJPJQTDYNZXKQF-UHFFFAOYSA-N

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Descrição geral

4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.

Aplicação

4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.

Pictogramas

Exclamation mark
GHS07

Palavra indicadora

Warning

Frases de perigo

H302,H315

Classificações de perigo

Acute Tox. 4 Oral - Skin Irrit. 2

Código de classe de armazenamento

10 - Combustible liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

201.2 °F

Ponto de fulgor (°C)

94 °C

Equipamento de proteção individual

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

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Anisole analytical standard

Supelco

96109

Anisole

4′-Bromoacetophenone 98%

Sigma-Aldrich

B56404

4′-Bromoacetophenone

4-Methoxyphenylboronic acid ≥95.0%

Sigma-Aldrich

417599

4-Methoxyphenylboronic acid

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