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Documentos

930989

Sigma-Aldrich

Cloreto de magnésio

99.999% (trace metals basis)

Sinônimo(s):

Magnesium dichloride hexahydrate

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About This Item

Fórmula linear:
MgCl2 · 6H2O
Número CAS:
Peso molecular:
203.30
Número MDL:
Código UNSPSC:
12352302
NACRES:
NA.21

Nível de qualidade

Ensaio

99.999% (trace metals basis)

forma

crystalline

pf

117 °C

solubilidade

H2O: soluble (highly soluble)
acetone: slightly soluble
alcohols: slightly soluble

cadeia de caracteres SMILES

O.O.O.O.O.O.Cl[Mg]Cl

InChI

1S/2ClH.Mg.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

chave InChI

DHRRIBDTHFBPNG-UHFFFAOYSA-L

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Descrição geral

Magnesium chloride hexahydrate is a colorless to white, crystalline salt. The salt is soluble in water and slightly soluble in ethanol, acetone, and pyridine. The hydrate loses water when heated to higher temperatures, but thermal dehydration to the anhydrous salt is not straightforward. Chemically, magnesium chloride is a weak Lewis acid. One of the most common and simplest routes to producing magnesium chloride is extraction from naturally occurring brine, for example by solar evaporation of sea water, which can be purified by solution chemistries.

Aplicação

One major application of high-purity magnesium chloride is in the synthesis of layered double hydroxides (LDH), which are high-surface area ionic clays. LDHs are studied for water filtration, among other applications, and usually consist of magnesium and aluminum ions because of the low toxicity of these metal cations. LDHs are synthesized from chloride salts using co-precipitation reactions, ion-exchange processes, and urea methods. Another application of high-purity magnesium chloride is as a reagent to dope or substitute magnesium ions into solid-state materials and nanoparticles. For example, Mg-doping in ZnO has shown to modulate its band structure and Mg-doping in lithium nickel cobalt manganese oxide helps suppress cation mixing and enables longer cycle lifetimes for its use as a cathode material.

Código de classe de armazenamento

13 - Non Combustible Solids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Effect of Mg doping on the structural and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode materials
Huang, Z., Wang, Z., et al.
Electrochimica Acta, 795-802, 182-182 (2015)
Preparation of Molybdenum Disulfide Coated Mg/Al Layered Double Hydroxide Composites for Efficient Removal of Chromium(VI)
Wang, J., Want, P., et al.
ACS sustainable chemistry & engineering, 5, 7165?7174-7165?7174 (2017)
A New Approach for Removing Anionic Organic Dyes from Wastewater Based on Electrostatically Driven Assembly
Sansuk, S., Srijaranai, S., et al.
Environmental Science & Technology, 50, 6477?6484-6477?6484 (2016)
Band gap engineering and enhanced photoluminescence of Mg doped ZnO nanoparticles synthesized by wet chemical route
Arshad, M., Ansari, M.M., et al.
Journal of Luminescence, 161, 275-280 (2015)

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