693979

(1E,2E)-1,2-Bis(2,6-Diisopropylphenylimino)ethane

90%

• Sinônimo(s): N,N′-Bis(2,6-diisopropylphenyl)-1,4-diazabutadiene, N,N′-Bis(2,6-diisopropylphenyl)ethanediimine, Glyoxal bis(2,6-diisopropylanil)
• Fórmula linear: (C₃H₇)₂C₆H₃NCHCHNC₆H₃(C₃H₇)₂
• Número CAS: 74663-75-5
• Peso molecular: 376.58
• Número MDL: MFCD03838856
• Código UNSPSC: 12352300
• ID de substância PubChem: 329761636
• NACRES: NA.22

Propriedades

• Ensaio: 90%
• Formulário: solid
• adequação da reação: reagent type: ligand
• pf: 105-109 °C
• cadeia de caracteres SMILES: CC(C)c1cccc(C(C)C)c1\N=C\C=N\c2c(cccc2C(C)C)C(C)C
• InChI: 1S/C26H36N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28-26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3/b27-15+,28-16+
• chave InChI: JWVIIGXMTONOFR-DPCVLPDWSA-N

Descrição

Aplicação

• Reactant in preparation of derived ruthenium olefin metathesis catalysts
• N-cyclic carbene ligand

Catalyst in:

• Palladium-catalyzed aerobic alc. oxidn. supported by a-diimine ligands
• Regioselective alkylation in presence of ruthenium-bisimine catalytic precursors
• N-arylation of aromatic amines
• Preparation of ruthenium nitrosyl alpha-diimine and iminoketone complexes as catalysts for transfer hydrogenation of ketones and atom transfer radical polymerization reactions

Informações de segurança

• Código de classe de armazenamento: 13 - Non Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable