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550787

Sigma-Aldrich

Vanadyl acetylacetonate

98%

Sinônimo(s):

VO(acac)2, Vanadium(IV)-oxy acetylacetonate

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About This Item

Fórmula linear:
OV(C5H7O2)2
Número CAS:
Peso molecular:
265.16
Beilstein:
4138236
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23
Preço e disponibilidade não estão disponíveis no momento.

Ensaio

98%

Formulário

solid

pf

235 °C (dec.) (lit.)

cadeia de caracteres SMILES

CC(=O)\C=C(\C)O[V](=O)O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/q;;;+2/p-2/b2*4-3-;;

chave InChI

JFHJZWAQYMGNBE-SUKNRPLKSA-L

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Aplicação

Vanadyl acetylacetonate may be used as a precursor for the preparation of vanadium dioxide thin films for applications in “intelligent” window coating and data storage.[1][2]

Pictogramas

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Palavra indicadora

Warning

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves


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Jack S Shamie et al.
ChemSusChem, 10(3), 533-540 (2016-11-20)
In this study, a new mechanism for the reduction of vanadyl acetylacetonate, VO(acac)
On the effects of electric fields in aerosol assisted chemical vapour deposition reactions of vanadyl acetylacetonate solutions in ethanol
Warwick MEA and Binions R
Journal of Nanoscience and Nanotechnology, 11(9), 8126-8131 (2011)
Szymon Kowalski et al.
International journal of molecular sciences, 20(2) (2019-01-13)
Pancreatic cancer is characterized by one of the lowest five-year survival rates. In search for new treatments, some studies explored several metal complexes as potential anticancer drugs. Therefore, we investigated three newly synthesized oxidovanadium(IV) complexes with 2-methylnitrilotriacetate (bcma3-), N-(2-carbamoylethyl)iminodiacetate (ceida3-)
Xinjian Shi et al.
Physical chemistry chemical physics : PCCP, 18(13), 9255-9261 (2016-03-16)
WO3-BiVO4 n-n heterostructures have demonstrated remarkable performance in photoelectrochemical water splitting due to the synergistic effect between the individual components. Although the enhanced functional capabilities of this system have been widely reported, in-depth mechanistic studies explaining the carrier dynamics of
Doped and un-doped vanadium dioxide thin films prepared by atmospheric pressure chemical vapour deposition from vanadyl acetylacetonate and tungsten hexachloride: the effects of thickness and crystallographic orientation on thermochromic properties.
Binions R,et al.
Journal of Materials Chemistry, 17, 4652-4660 (2007)

Artigos

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. Below is a list of the most commonly used oxidizing and reducing agents currently available in our catalog.

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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