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50053

Sigma-Aldrich

Cloreto de glicidiltrimetilamônio

technical, ≥90% (calc. based on dry substance, AT)

Sinônimo(s):

Cloreto de (2,3-epoxipropil)trimetilamônio

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About This Item

Fórmula empírica (Notação de Hill):
C6H14ClNO
Número CAS:
Peso molecular:
151.63
Beilstein:
3914931
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.22
Preço e disponibilidade não estão disponíveis no momento.

grau

technical

Nível de qualidade

Ensaio

≥90% (calc. based on dry substance, AT)

Impurezas

2-4% chlorohydrin
20-25% water

densidade

1.13 g/mL at 20 °C (lit.)

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

[Cl-].C[N+](C)(C)CC1CO1

InChI

1S/C6H14NO.ClH/c1-7(2,3)4-6-5-8-6;/h6H,4-5H2,1-3H3;1H/q+1;/p-1

chave InChI

PUVAFTRIIUSGLK-UHFFFAOYSA-M

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Descrição geral

O cloreto de glicidiltrimetilamônio (GTMAC) é um agente de cationização usado comumente para modificação de amido.[1]

Aplicação

O cloreto de glicidiltrimetilamônio pode ser usado como agente de derivatização para sintetizar cloreto de N-(2-hidroxipropil)-3-trimetilamônio quitosana (HTCC), um derivado de quitosana solúvel em água, reagindo com a quitosana. O HTCC pode formar filmes nanocompósitos com nanopartículas de prata que exibem boa propriedade antimicrobiana e transparência óptica.[2] Amidos catiônicos também podem ser preparados pela derivatização de amido com GTMAC.[3]

Atenção

Hidrólise no armazenamento (aproximadamente 3,5%/mês a 20 °C)

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Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Sens. 1 - STOT RE 2 - STOT SE 2

Órgãos-alvo

Kidney

Código de classe de armazenamento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

338.0 °F - closed cup

Ponto de fulgor (°C)

170 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Xinlu Wang et al.
Frontiers in bioengineering and biotechnology, 7, 360-360 (2020-01-11)
Wound immersion in seawater with high salt, high sodium, and a high abundance of pathogenic bacteria, especially gram-negative bacteria, can cause serious infections and difficulties in wound repair. The present study aimed to prepare a composite hydrogel composed of hyaluronic
Zhao-Xiang Peng et al.
Antimicrobial agents and chemotherapy, 55(2), 860-866 (2010-12-08)
Our previous study (Z. X. Peng et al., Carbohydr. Polym. 81:275-283, 2010) demonstrated that water-soluble quaternary ammonium salts, which are produced by the reaction of chitosan with glycidyl trimethylammonium chloride, provide chitosan derivatives with enhanced antibacterial ability. Because biofilm formation
Sirlei Rosa et al.
Journal of hazardous materials, 155(1-2), 253-260 (2008-01-09)
Adsorption of reactive orange 16 by quaternary chitosan salt (QCS) was used as a model to demonstrate the removal of reactive dyes from textile effluents. The polymer was characterized by infrared (IR), energy dispersive X-ray spectrometry (EDXS) analyses and amount
Le Thi Tuyet Nhung et al.
Polymers, 12(11) (2020-11-21)
An efficient and effective process for the production of high-performance anion exchange membranes (AEMs) is necessary for the commercial application of fuel cells. Therefore, in this study, quaternized poly vinylbenzyl chloride (QVBC) and polysulfone were composited with glycidyltrimethylammonium-chloride-quaternized chitosan (QCS)
Wioletta Błaszczak et al.
Foods (Basel, Switzerland), 9(5) (2020-05-28)
Light microscopy (LM) is commonly used in the study of biological materials to determine the morphology of cells and tissues. The potential of this technique for studying the structure of food products is also recognized but less known. Especially rare

Questions

1–4 of 4 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. From this information “Caution hydrolysis on storage (approx. 3.5%/month at 20°C)”  If I keep in storage -18 °C it’s can keep product from approx.? Or reduce some loss?

    1 answer
    1. The recommended storage temperature for the product is 2-8 °C. The retest period for this item is approximately one year from the quality release date when stored in these conditions. There is no stability information available regarding storage at -18°C.

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  4. >90% Glycidyltrimethylammonium Chloride (#50053) has a water content between 20-25%. What would be the refractive index at a water content of 20 and 25%?

    1 answer
    1. The refractive index is not determined.

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