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Documentos Principais

449504

Sigma-Aldrich

Bis(trifluorometano)sulfonimida

Sinônimo(s):

Bis(trifluorometilsulfonil)amina, Bistrifluorometanossulfonimidato de lítio

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About This Item

Fórmula linear:
CF3SO2NLiSO2CF3
Número CAS:
Peso molecular:
287.09
Beilstein:
6625414
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.22
Preço e disponibilidade não estão disponíveis no momento.

pf

234-238 °C (lit.)

grupo funcional

fluoro

cadeia de caracteres SMILES

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

chave InChI

QSZMZKBZAYQGRS-UHFFFAOYSA-N

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Aplicação

Bis(trifluoromethane)sulfonimide lithium salt (Li-TFSI) can be used:
  • As a chemical additive for improving the power conversion efficiencies in porphyrin-based organic solar cells.[1]     
  • As a reagent in the preparation of imidazolium core bearing monomer ionic liquids to develop polymerized ionic liquids.[2]
  • For the preparation of a chiral imidazolium salt via anion metathesis of the corresponding triflate.[3]       
  • In the synthesis of solid polymer electrolytes for lithium-ion batteries.[4][5] 
  • In the synthesis of polyelectrolyte reusable homogenous catalysts, which are used in the Diels–Alder reactions between isoprene and a variety of dienophiles.[6]
  • Used in the preparation of electrolytes for lithium batteries[7][8][9] and novel rare-earth Lewis acid catalysts.[10]

Outras notas

For a review on fluorine containing nitrogen acids, see Coordination Chemistry Reviews.[11]

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

Órgãos-alvo

Nervous system

Código de classe de armazenamento

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Poly (ethylene oxide carbonates) solid polymer electrolytes for lithium batteries
Meabe L, et al.
Electrochimica Acta, 264, 367-375 (2018)
3-[2-(Oxiran-2-yl) ethyl]-1-{4-[(2-oxiran-2-yl) ethoxy] benzyl} imidazolium bis (Trifluoromethane) sulfonimide
Chardin C, et al.
Molbank, 2018(1), M974-M974 (2018)
Susana Arrechea et al.
Nanoscale, 8(41), 17953-17962 (2016-10-21)
Two new conjugated acceptor-π-donor-π-acceptor (A-π-D-π-A) porphyrins have been synthesised using 3-ethylrhodanine (1a) or dicyanovinylene (1b) groups as acceptor units. Their optical and electrochemical properties made these materials excellent electron donors along with PC71BM as the acceptor for solution-processed bulk heterojunction
Polyelectrolyte-catalyzed Diels-Alder reactions
Pothanagandhi N, et al.
Reactive and Functional Polymers, 106, 132-136 (2016)
Reliability of lithium batteries with crosslinked polymer electrolytes
Borghini MC, et al.
Electrochimica Acta, 41, 2369-2369 (1996)

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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the purity?

    1 answer
    1. Product 449504 is not tested for purity. The product undergoes IR testing as well as carbon, hydrogen, and fluorine NMR to confirm its identity but minor impurities may be present.

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