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424072

Sigma-Aldrich

N,N,N′,N′-Tetraethyldiethylenetriamine

technical grade, 90%

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About This Item

Fórmula linear:
[(C2H5)2NCH2CH2]2NH
Número CAS:
123-12-6
Peso molecular:
215.38
Número CE:
204-603-1
Número MDL:
MFCD00039880
Código UNSPSC:
12352100
ID de substância PubChem:
24866550
NACRES:
NA.22

grau

technical grade

Ensaio

90%

forma

liquid

índice de refração

n20/D 1.448 (lit.)

pb

130-135 °C (lit.)

densidade

0.837 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

CCN(CC)CCNCCN(CC)CC

InChI

1S/C12H29N3/c1-5-14(6-2)11-9-13-10-12-15(7-3)8-4/h13H,5-12H2,1-4H3

chave InChI

UICCSKORMGVRCB-UHFFFAOYSA-N

Descrição geral

N,N,N′,N′-Tetraethyldiethylenetriamine (TEDETA) is an N-substituted ethylenediamine ligand. Its boiling point, density and refractive index have been determined.

Aplicação

N,N,N′,N′-Tetraethyldiethylenetriamine (TEDETA) has been used in the following studies:
  • As N-substituted ethylenediamine ligand in the synthesis of [Ni(Et4dien)(NO2)2] (Et4dien=N,N,N′,N′-tetraethyldiethylenetriamine).
  • As a reagent in the synthesis of adamantanyl connector, (2-(1-carbamoylmethyladamantane)di(ethyl(diethylmethylammonium))dichloride).
  • As a reagent in the synthesis of aminated macroligand.
  • As a reagent in the synthesis of precipiton ligand.
  • As a multimodal ligand in the synthesis of P(S-DVB)-g-P(S-GMA)- TEDETA beads (poly(styrene-divinylbenzene)-graft-poly(styrene-glycidylmethacrylate)).

Pictogramas

Exclamation mark
GHS07

Palavra indicadora

Warning

Frases de perigo

H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

8A - Combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

208.4 °F - closed cup

Ponto de fulgor (°C)

98 °C - closed cup

Equipamento de proteção individual

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Gulay Bayramoglu et al.
Bioresource technology, 102(4), 3653-3661 (2011-01-05)
Fibrous poly(styrene-d-glycidylmethacrylate) (P(S-GMA)) brushes were grafted on poly(styrene-divinylbenzene) (P(S-DVB)) beads using surface initiated-atom transfer radical polymerization (SI-ATRP). Tetraethyldiethylenetriamine (TEDETA) ligand was incorporated on P(GMA) block. The multi-modal ligand attached beads were used for reversible immobilization of catalase. The influences of
Metastable linkage isomerism in [Ni(Et4dien)(NO2)2]: a combined thermal and photocrystallographic structural investigation of a nitro/nitrito interconversion.
Lauren E Hatcher et al.
Angewandte Chemie (International ed. in English), 50(36), 8371-8374 (2011-07-23)
Use of precipitons for copper removal in atom transfer radical polymerization.
Honigfort ME, et al.
Macromolecules, 35(13), 4849-4851 (2002)
Virginie Burckbuchler et al.
Bioconjugate chemistry, 19(12), 2311-2320 (2008-12-05)
In this study, we investigated whether a cyclodextrin polymer (polybetaCD) complexed with cationic adamantyl derivatives (Ada) could be used as a vector for gene delivery. DNA compaction as a function of adamantyl/DNA phosphate ratio (A/P) by this new class of
Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide.
Grignard B, et al.
European Polymer Journal, 44(3), 861-871 (2008)
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