359068

(−)-Dimethyl 2,3-O-isopropylidene-L-tartrate

97%

• Sinônimo(s): (4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic acid dimethyl ester, Dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate
• Fórmula empírica (Notação de Hill): C₉H₁₄O₆
• Número CAS: 37031-29-1
• Peso molecular: 218.20
• Beilstein: 15406
• Número MDL: MFCD00066218
• Código UNSPSC: 12352005
• ID de substância PubChem: 24862049
• NACRES: NA.22

Propriedades

• Ensaio: 97%
• forma: liquid
• atividade óptica: [α]20/D −54°, neat
• índice de refração: n20/D 1.439 (lit.)
• pb: 150 °C/19 mmHg (lit.)
• densidade: 1.190 g/mL at 20 °C (lit.)
• cadeia de caracteres SMILES: COC(=O)[C@@H]1OC(C)(C)O[C@H]1C(=O)OC
• InChI: 1S/C9H14O6/c1-9(2)14-5(7(10)12-3)6(15-9)8(11)13-4/h5-6H,1-4H3/t5-,6-/m1/s1
• chave InChI: ROZOUYVVWUTPNG-PHDIDXHHSA-N

Descrição

Aplicação

(-)-Dimethyl 2,3-O-isopropylidene-L-tartrate may be used as a starting material in the total synthesis of (+)-migrastatin and also in the synthesis of a structural analog of S-ribosylhomocysteinase (LuxS), which acts as a potent competitive inhibitor against LuxS.

Valuable building block for TADDOL chiral auxiliaries, dipyridine ligands, and threitols.

Informações de segurança

• Código de classe de armazenamento: 10 - Combustible liquids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 230.0 °F - closed cup
• Ponto de fulgor (°C): 110 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Gloves