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Sigma-Aldrich

Sodium cyclopentadienylide

Sodium cyclopentadienylide

2.4 M in THF

Sinônimo(s):

Cyclopentadienylsodium solution

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About This Item

Fórmula empírica (Notação de Hill):
C5H5Na
Número CAS:
Peso molecular:
88.08
Beilstein:
969542
Número MDL:
Código UNSPSC:
12161600
ID de substância PubChem:
NACRES:
NA.22
Preço e disponibilidade não estão disponíveis no momento.

Formulário

liquid

Nível de qualidade

adequação da reação

reagent type: ligand

concentração

2.4 M in THF

densidade

0.938 g/mL at 25 °C

cadeia de caracteres SMILES

[Na]C1C=CC=C1

InChI

1S/C5H5.Na/c1-2-4-5-3-1;/h1-5H;

chave InChI

PDTZVKVFAJGNRV-UHFFFAOYSA-N

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Aplicação

It can also be used in the synthesis of:
  • Ruthenocene and fullerene molecular hybrid, Ru(η5- C60Me5)( η5-C5H5) (bucky ruthenocene).[1]
  • Allyl-substituted cyclopentadiene by palladium-catalyzed allylic alkylation.[2]
  • Bis(cyclopentadienyl)zirconium dichloride which is used as a catalyst in the synthesis of bis(indolyl)methanes and alkylation of heteroaryls.[3]
  • Cp-cobaltacycles from diphenylphosphinoalkynes and CoCl(PPh3)3.[4]
Sodium cyclopentadienylide is a useful reagent for the preparation of metallocenes[5][6] and cyclopentadienyl metal complexes.[7]

Palavra indicadora

Danger

Classificações de perigo

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Órgãos-alvo

Central nervous system, Respiratory system

Perigos de suplementos

Código de classe de armazenamento

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

1.4 °F - closed cup

Ponto de fulgor (°C)

-17 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Visite a Biblioteca de Documentos

Synthesis and reactivity of bucky ruthenocene Ru(η5- C60Me5)( η5-C5H5).
Matsuo Y, et al.
Chemistry Letters (Jpn), 33(1), 68-69 (2003)
Journal of the Chemical Society. Chemical Communications, 2007-2007 (1994)
Bis (cyclopentadienyl) zirconium dichloride for alkylation of heteroaromatics and synthesis of bis (indolyl) methanes.
Kantam ML, et al.
Catalysis Letters, 98(2-3), 117-121 (2004)
Journal of Organometallic Chemistry, 467, 75-75 (1994)
Journal of Organometallic Chemistry, 691, 5831-5831 (2006)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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