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282316

Sigma-Aldrich

Perfluoro-1,3-dimethylcyclohexane

technical grade, 80%

Sinônimo(s):

Decafluoro-1,3-bis(trifluoromethyl)cyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane (cis+trans)

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About This Item

Fórmula linear:
C6F10(CF3)2
Número CAS:
335-27-3
Peso molecular:
400.06
Beilstein:
2064147
Número CE:
206-386-9
Número MDL:
MFCD00001469
Código UNSPSC:
12352100
ID de substância PubChem:
24857038
NACRES:
NA.22

grau

technical grade

densidade de vapor

14 (vs air)

Ensaio

80%

forma

liquid

índice de refração

n20/D 1.3 (lit.)

pb

101-102 °C (lit.)

pf

−55 °C (lit.)

densidade

1.828 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(C(F)(F)F)C1(F)F

InChI

1S/C8F16/c9-1(7(19,20)21)3(11,12)2(10,8(22,23)24)5(15,16)6(17,18)4(1,13)14

chave InChI

LOQGSOTUHASIHI-UHFFFAOYSA-N

Descrição geral

Quenching of the second excited singlet state of xanthione in inert, nonpolar perfluoro-1,3-dimethylcyclohexane has been studied using picosecond time-resolved fluorescence decay methods.

Aplicação

Perfluoro-1,3-dimethylcyclohexane has been used in:
  • the preparation of amorphous fluorocarbon films by plasma polymerization
  • hydroformylation of linear terminal alkenes using rhodium based catalysts under fluorous biphasic conditions in the presence and absence of toluene

Pictogramas

Exclamation mark
GHS07

Palavra indicadora

Warning

Frases de perigo

H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

10 - Combustible liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

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Hydroformylation in perfluorinated solvents; improved selectivity, catalyst retention and product separation.
<BIG>Foster DF, et al. </BIG>
Tetrahedron, 58(20), 3901-3910 (2002)
Transient effects in the fluorescence quenching of xanthione in perfluoro-1, 3-dimethylcyclohexane.
Maciejewski A, et al.
International Journal of Radiation Applications and Instrumentation, Part B: Nuclear Medicine and Biology, 39(1), 155-158 (1992)
Electrical and optical properties of amorphous fluorocarbon films prepared by plasma polymerization of perfluoro-1, 3-dimethylcyclohexane.
Weber A, et al.
Journal of Vacuum Science & Technology. A, Vacuum, Surfaces, And Films, 16(4), 2120-2124 (1998)
Meagan M Gadzuk-Shea et al.
The journal of physical chemistry. B, 122(43), 9947-9955 (2018-10-24)
Understanding the structures of proteins in the gas phase is essential for using gas-phase measurements to infer the properties of proteins in solution. Using serum albumin as a model, this study aims to expand our understanding of this relationship for
Antonelle Pardo et al.
Journal of chromatography. A, 1364, 128-139 (2014-09-10)
Molecularly imprinted polymers (MIPs) based on quercetin and synthesized by either bulk, precipitation or suspension polymerization were characterized in terms of size and shape by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). After a study of rebinding protocols

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