Pular para o conteúdo
Merck
Todas as fotos(2)

Key Documents

View All Documentation

208353

Sigma-Aldrich

Molybdenum(V) chloride

95%

Sinônimo(s):

Molybdenum pentachloride, Pentachloromolybdenum

Faça loginpara ver os preços organizacionais e de contrato
Todas as fotos(2)

About This Item

Fórmula linear:
MoCl5
Número CAS:
10241-05-1
Peso molecular:
273.21
Número MDL:
MFCD00003467
Código UNSPSC:
12352302
ID de substância PubChem:
24852509
NACRES:
NA.23

pressão de vapor

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

Nível de qualidade

100

Ensaio

95%

forma

powder

adequação da reação

reagent type: catalyst
core: molybdenum

Impurezas

<0.5% insoluble matter

pb

268 °C (lit.)

pf

194 °C (lit.)

densidade

2.928 g/mL at 25 °C (lit.)

aplicação(ões)

battery manufacturing

cadeia de caracteres SMILES

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

chave InChI

GICWIDZXWJGTCI-UHFFFAOYSA-I

Procurando produtos similares? Visita Guia de comparação de produtos

Categorias relacionadas

Descrição geral

Molybdenum(V)chloride is a Lewis acid widely used as a catalyst and reagent in many organicreactions. It can be prepared by direct chlorination of molybdenum metal or byrefluxing thionyl chloride and MoO3.

Aplicação

Molybdenum(V) chloride can be used as an efficient catalyst for:
  • Condensation of nitrobenzene with alcohols and C-C coupling of alkenyllithium reagents.
  • Direct amidation of benzylic alcohols with sulfonamides and carbamates.
It can be used for the chlorination of alkyl halides, alkenes, and alkynes.

It can also be used as aprecursor to synthesize alumina/molybdenum nanocomposites and methylenemolybdenumreagents for chemoselective carbonyl alkenation.

Pictogramas

Health hazardCorrosion
GHS08,GHS05

Palavra indicadora

Danger

Frases de perigo

H314,H351

Classificações de perigo

Carc. 2 - Eye Dam. 1 - Skin Corr. 1B

Código de classe de armazenamento

8A - Combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

Já possui este produto?

Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.

Visite a Biblioteca de Documentos

Kristina Hackeloer et al.
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
Mladen Litvić et al.
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose
Kumar, S. Manickam, M.
Chemical Communications (Cambridge, England), 1615-1615 (1997)
H I Ogawa et al.
Mutation research, 320(1-2), 133-140 (1994-01-01)
A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and
Simon Trosien et al.
Organic letters, 14(12), 2976-2979 (2012-06-05)
The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular

Nossa equipe de cientistas tem experiência em todas as áreas de pesquisa, incluindo Life Sciences, ciência de materiais, síntese química, cromatografia, química analítica e muitas outras.

Entre em contato com a assistência técnica