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203548

Sigma-Aldrich

Lanthanum(III) nitrate hexahydrate

99.999% trace metals basis

Sinônimo(s):

Nitric acid, lanthanum (III) salt, hexahydrate

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About This Item

Fórmula linear:
La(NO3)3 · 6H2O
Número CAS:
Peso molecular:
433.01
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.23

Ensaio

99.999% trace metals basis

forma

solid

adequação da reação

reagent type: catalyst
core: lanthanum

Impurezas

≤15.0 ppm Trace Rare Earth Analysis

pf

65-68 °C

cadeia de caracteres SMILES

[La+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

chave InChI

GJKFIJKSBFYMQK-UHFFFAOYSA-N

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Descrição geral

Lanthanum(III) nitrate hexahydrate is a transition metal catalyst widely used in many organic transformations such as chemoselective deprotection of acetonides, acetylation of alcohols, phenols, and amines with acetic anhydride, and synthesis of α-amino nitriles. It can also be used as a precursor in the preparation of lanthanum-based nanoparticles.

Aplicação

Lanthanum(III) nitrate hexahydrate can be used as a catalyst in the synthesis of:
  • α-aminonitriles by a one-pot three-component coupling of the carbonyl compound, amine, and TMSCN.
  • Acetals and geminal diacetates (acylals)from aldehydes.
  • Bis(indolyl) methanes under solvent‐free conditions.
It can also be used as a starting material for the electrochemical synthesis of LaMnO3 thin films and solvothermal synthesis of doped lanthanide oxysulfide (La2O2S).

Características e benefícios

  • Thermal stability
  • Low toxicity
  • Mild reaction condition
  • Chemoselectivity
  • Low cost

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2

Código de classe de armazenamento

5.1B - Oxidizing hazardous materials

Classe de risco de água (WGK)

WGK 2

Equipamento de proteção individual

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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J Tyler Mefford et al.
Physical chemistry chemical physics : PCCP, 21(6), 3327-3338 (2019-01-29)
Perovskite oxides are active room-temperature bifunctional oxygen electrocatalysts in alkaline media, capable of performing the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) with lower combined overpotentials relative to their precious metal counterparts. However, their semiconducting nature necessitates the
Wen-Feng Zhao et al.
Dalton transactions (Cambridge, England : 2003), 41(33), 10091-10096 (2012-08-02)
The reaction between polyoxometalate (POM) [TBA](12)[WZn{Zn(H(2)O)}(2)(ZnW(9)O(34))(2)] (TBA = tetrabutyl ammonium) and lanthanide (Ln) nitrate (Ln = La, Eu and Tb) in a mixed solvent of CH(3)CN and DMF yielded three noncentrosymmetric diamondoid Ln-POM solid materials, {[Ln(2)(DMF)(8)(H(2)O)(6)][ZnW(12)O(40)]}·4DMF (Ln-POM; Ln = La
L P Lopatina et al.
Biofizika, 50(6), 1120-1124 (2005-12-20)
The influence of lanthanoids on exocytosis was investigated. It was shown that gadolinium increases the spontaneous release of the glutamate nonmetabolizing analogue [3H]D-aspartate. It was established using the fluorescent dye acridine orange that gadolinium and lanthanum induce exocytosis. The effect
Emanuela Mazzon et al.
Shock (Augusta, Ga.), 25(5), 515-521 (2006-05-09)
Small intestine permeability is frequently altered in inflammatory bowel diseases and may be caused by the translocation of intestinal toxins through leaky small intestine tight junctions (TJs) and adherence. Thus, the aim of the present study was to examine the
Hartwig Wolburg et al.
Histochemistry and cell biology, 130(1), 127-140 (2008-03-15)
The olfactory ensheathing (glial) cells (OECs) have been identified to be useful candidate cells to support regeneration after being transplanted into injured fiber tracts of the central nervous system. We investigated by means of immunocytochemistry and freeze-fracturing the morphology and

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