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Merck
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Documentos

194484

Sigma-Aldrich

O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride

≥98%

Sinônimo(s):

PFBHA·HCl

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About This Item

Fórmula linear:
C6F5CH2ONH2·HCl
Número CAS:
57981-02-9
Peso molecular:
249.57
Beilstein:
4031190
Número CE:
261-057-7
Número MDL:
MFCD00012953
Código UNSPSC:
12352100
ID de substância PubChem:
24851655
NACRES:
NA.22

Ensaio

≥98%

forma

solid

pf

227 °C (subl.) (lit.)

solubilidade

water: soluble 50 mg/mL, clear to slightly hazy, colorless

cadeia de caracteres SMILES

Cl.NOCc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C7H4F5NO.ClH/c8-3-2(1-14-13)4(9)6(11)7(12)5(3)10;/h1,13H2;1H

chave InChI

HVMVKNXIMUCYJA-UHFFFAOYSA-N

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Aplicação

O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride is used:
  • In the preparation of oximes of steroids-bearing keto group.
  • As a derivatization reagent in the determination of thromboxane B2, prostaglandins, amygdalin, and a variety of aldehydes, ketones, and acids.
It is a versatile reagent used for the detection of carbonyl-containing compounds by GC, GC-MS, and other methods.

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)

Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

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Sigma-Aldrich

480894

O-(Tetrahydro-2H-pyran-2-yl)hydroxylamine

2,4-Dinitrophenylhydrazine reagent grade, 97%

Sigma-Aldrich

D199303

2,4-Dinitrophenylhydrazine

Vicente Ferreira et al.
Journal of chromatography. A, 1122(1-2), 255-265 (2006-05-20)
This work presents a thorough study of some aspects critical to the quantitative performance of methods for the determination of volatile aldehydes previously derivatized to pentafluorobenzyl hydroxylamine oximes. The conclusions of the study are further applied to the validation of
Raya Ahmed et al.
Cell reports, 33(11), 108501-108501 (2020-12-17)
A central paradigm in the field of lymphocyte biology asserts that replicatively senescent memory T cells express the carbohydrate epitope CD57. These cells nonetheless accumulate with age and expand numerically in response to persistent antigenic stimulation. Here, we use in vivo deuterium
T Gabrio et al.
Journal of chromatography. A, 1046(1-2), 293-296 (2004-09-25)
To avoid microbiological decay pool water is disinfected, a procedure which results into a lot of disinfection by-products, like carbonyl compounds, as well as a large number of others. The carbonyl compounds dissolved in pool water were derivatisized with O-(2,3,4,5,6-pentafluorobenzyl)hydroxyamine
Petr Vesely et al.
Journal of agricultural and food chemistry, 51(24), 6941-6944 (2003-11-13)
A new, fast, sensitive, and solventless extraction technique was developed in order to analyze beer carbonyl compounds. The method was based on solid-phase microextraction with on-fiber derivatization. A derivatization agent, O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBOA), was absorbed onto a divinyl benzene/poly(dimethylsiloxane) 65-microm fiber
Chunhui Deng et al.
Journal of separation science, 28(2), 172-176 (2005-03-10)
A simple, rapid, sensitive, and solvent-free method was developed for determination of plant-signalling compounds, the three C6-aldehydes hexanal, (Z)-3-hexenal, and (E)-2-hexenal, in tomato plant emission by gas chromatography-mass spectrometry (GC-MS) and solid-phase microextraction (SPME) with on-fiber derivatization. In this method
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