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171441

Sigma-Aldrich

Trifluoroiodomethane

99%

Sinônimo(s):

Iodotrifluoromethane, Perfluoromethyl iodide, Trifluoromethyl iodide

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About This Item

Fórmula empírica (Notação de Hill):
CF3I
Número CAS:
2314-97-8
Peso molecular:
195.91
Beilstein:
1732740
Número CE:
219-014-5
Número MDL:
MFCD00001060
Código UNSPSC:
12142100
ID de substância PubChem:
24850061
NACRES:
NA.22

Ensaio

99%

pb

−22.5 °C (lit.)

pf

<−78 °C (lit.)

cadeia de caracteres SMILES

FC(F)(F)I

InChI

1S/CF3I/c2-1(3,4)5

chave InChI

VPAYJEUHKVESSD-UHFFFAOYSA-N

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Aplicação

Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,ß-unsaturated ketones.

Embalagem

Supplied in a Sure/Pac™ cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

Informações legais

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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Z146811

Hose adapter, brass

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Palavra indicadora

Warning

Frases de perigo

H280,H341,H420

Classificações de perigo

Muta. 2 - Ozone 1 - Press. Gas Compr. Gas

Código de classe de armazenamento

2A - Gases

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves

Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

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C Stefan Lehmann et al.
Faraday discussions, 153, 173-187 (2011-01-01)
The control of multichannel ionic fragmentation dynamics in CF3I is studied by femtosecond pulse shaping and velocity map photoelectron photoion coincidence imaging. When CF3I is photoexcited with femtosecond laser pulses around 540 nm there are two major ions observed in
D E Dodd et al.
Inhalation toxicology, 11(11), 1041-1055 (1999-11-24)
CF(3)I is being considered by the U.S. Air Force as a replacement for Halon 1301 for fire-extinguishing requirements in unoccupied spaces. The purpose of this study was to determine and evaluate the potential for CF(3)I to produce reproductive toxicity and
D E Dodd et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 35(1), 64-77 (1997-01-01)
Trifluoroiodomethane (CF3I) is being considered as a replacement compound for halon fire suppressants. Its structure is similar to that of Halon 1301 (CF3Br), but it has very low ozone depletion potential compared to CF3Br. As part of the process of
Andreas Vargas Jentzsch et al.
Nature communications, 3, 905-905 (2012-06-21)
In biology and chemistry, the transport of anions across lipid bilayer membranes is usually achieved by sophisticated supramolecular architectures. Significant size reduction of transporters is hampered by the intrinsically hydrophilic nature of typical anion-binding functionalities, hydrogen-bond donors or cations. To
Kelvin Anggara et al.
Science advances, 4(10), eaau2821-eaau2821 (2018-10-13)
Collision geometry is central to reaction dynamics. An important variable in collision geometry is the miss-distance between molecules, known as the "impact parameter." This is averaged in gas-phase molecular beam studies. By aligning molecules on a surface prior to electron-induced
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Artigos

Tetrakis(dimethylamino)ethylene (TDAE)

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)

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