Accéder au contenu
Merck
Toutes les photos(4)

Key Documents

View All Documentation

228036

Sigma-Aldrich

OXONE®, monopersulfate compound

Synonyme(s) :

Potassium peroxymonosulfate

Se connecterpour consulter vos tarifs contractuels et ceux de votre entreprise/organisme
Toutes les photos(4)

About This Item

Formule linéaire :
KHSO5 · 0.5KHSO4 · 0.5K2SO4
Numéro CAS:
70693-62-8
Poids moléculaire :
307.38
Numéro MDL:
MFCD00040551
Code UNSPSC :
12352300
ID de substance PubChem :
57648006
Nomenclature NACRES :
NA.21

Pression de vapeur

<0.0000017 hPa

Niveau de qualité

200

Forme

powder

Pertinence de la réaction

reagent type: oxidant

Concentration

>4.0% (active oxygen basis (by Na2S2O3, titration))

pH

2.1 (77 °C, 30 g/L)

Chaîne SMILES 

[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O

InChI

1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

Clé InChI

HJKYXKSLRZKNSI-UHFFFAOYSA-I

Vous recherchez des produits similaires ? Visite Guide de comparaison des produits

Catégories apparentées

Description générale

OXONE®, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant.

Application

A rapid, efficient synthesis of oxaziridines from imines using buffered OXONE has been reported. Also used to study fading of an artist′s colorants.
OXONE®, monopersulfate compound may be used as an alternative to transition-metal oxidants for the conversion of aldehydes to carboxylic acids or esters.
Oxidant used for halogenation of α,β-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.
Oxidant used for halogenation of a,b-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.

2-Iodoxybenzenesulfonic Acid as an Extremely Active Catalyst for the Selective Oxidation of Alcohols to Aldehydes, Ketones, Carboxylic Acids, and Enones with Oxone

A Convenient Halogenation of α,β-Unsaturated Carbonyl Compounds with OXONE® and Hydrohalic Acid (HBr, HCl)

Informations légales

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

Pictogrammes

CorrosionExclamation markEnvironment
GHS05,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H302,H314,H411

Classification des risques

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Classe de danger pour l'eau (WGK)

WGK 3

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
0000400058
0000375143
0000367257
0000358085
0000355727

Vous ne trouvez pas la bonne version ?

Si vous avez besoin d'une version particulière, vous pouvez rechercher un certificat spécifique par le numéro de lot.

Rechercher un(e) COA

Déjà en possession de ce produit ?

Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Les clients ont également consulté

Slide 1 of 5

1 of 5

4-Pentenoic acid 97%

Sigma-Aldrich

245925

4-Pentenoic acid

(&#8722;)-Borneol analytical standard

Supelco

15598

(−)-Borneol

Camphor 96%

Sigma-Aldrich

148075

Camphor

Potassium persulfate ACS reagent, &#8805;99.0%

Sigma-Aldrich

216224

Potassium persulfate

(&#8722;)-Borneol phyproof&#174; Reference Substance

PHL89583

(−)-Borneol

Yifu Li et al.
Bioresource technology, 262, 294-301 (2018-05-08)
In this study, zero valent iron (ZVI) activated peroxymonosulfate (PMS) as novel technique (i.e. ZVI-PMS technology) was employed to enhance sludge dewatering. In optimal sludge dewatering conditions of ZVI and KHSO5 dosages, the specific resistance to filtration (SRF) was reduced
Atmos. Environ., Part A, 27A, 765-765 (1993)
Yao-Hui Huang et al.
Journal of hazardous materials, 170(2-3), 1110-1118 (2009-06-23)
In order to generate powerful radicals as oxidizing species for the complete decolorization and degradation of azo dye Reactive Black B (RBB) at near neutral pH (pH 6), homogeneous activation of peroxymonosulfate (Oxone: PMS) by the trace Co2+-catalysts was explored.
Yi-Fong Huang et al.
Journal of hazardous materials, 167(1-3), 418-426 (2009-02-14)
This study investigated the degradation and mineralization of Bisphenol A (BPA) at pH 7, taken as a model compound in the presence of the trace metal-ions, Co(2+), and peroxymonosulfate (Oxone: PMS). We took advantage of the high oxidation-reduction potential of
Benjamin R Travis et al.
Organic letters, 5(7), 1031-1034 (2003-03-28)
[reaction: see text] A highly efficient, mild, and simple protocol is presented for the oxidation of aldehydes to carboxylic acids utilizing Oxone as the sole oxidant. Direct conversion of aldehydes in alcoholic solvents to their corresponding ester products is also
Afficher tous les articles scientifiques apparentés

Articles

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

Notre équipe de scientifiques dispose d'une expérience dans tous les secteurs de la recherche, notamment en sciences de la vie, science des matériaux, synthèse chimique, chromatographie, analyse et dans de nombreux autres domaines..

Contacter notre Service technique