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901409

Sigma-Aldrich

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

Synonyme(s) :

Iridium(III) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate

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About This Item

Formule empirique (notation de Hill):
C42H40F10IrN4P
Numéro CAS:
1335047-34-1
Poids moléculaire :
1013.97
Code UNSPSC :
12161600
Nomenclature NACRES :
NA.22

Forme

solid

Niveau de qualité

100

Pertinence de la réaction

core: iridium
reagent type: catalyst

Capacité de réaction

reaction type: Photocatalysis

Activation du photocatalyseur

450 nm

Catégories apparentées

Application

[Ir(dF(Me)ppy)2(dtbbpy)]PF6 is a photocatalyst readily facilitates hydroamination of olefins as well as the decarboxylative arylation and vinylation of carboxylic acids via metallaphotoredox catalysis.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Autres remarques

Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines

Merging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halides

Enhanced luminescent iridium(III) complexes bearing aryltriazole cyclometallated ligands

Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

747769

[Ir(dtbbpy)(ppy)2]PF6

747793

(Ir[dF(CF3)ppy]2(dtbpy))PF6

804215

[Ir{dFCF3ppy}2(bpy)]PF6

900540

Ir(dFppy)3

900539

Ir[p-F(t-Bu)-ppy]3

900538

Ir(p-F-ppy)3

900570

Ir[dF(t-Bu)-ppy]3

901368

[Ir(dFppy)2(dtbbpy)]PF6

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%

904694

Ir(p-CF3-ppy)3, ≥95%

905518

Ir(dFFppy)2(dtbbpy)PF6

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

911607

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

912948

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

922897

[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

925497

[Ir(dFOMeppy)2(dtbbpy)]PF6, ≥95%

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Certificats d'analyse (COA)

Recherchez un Certificats d'analyse (COA) en saisissant le numéro de lot du produit. Les numéros de lot figurent sur l'étiquette du produit après les mots "Lot" ou "Batch".

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Consulter la Bibliothèque de documents

Victoria Dimakos et al.
Journal of the American Chemical Society, 141(13), 5149-5153 (2019-03-23)
Diphenylborinic acid serves as a cocatalyst for site- and stereoselective C-H alkylation reactions of carbohydrates under photoredox conditions using quinuclidine as the hydrogen atom transfer mediator. Products arising from selective abstraction of the equatorial hydrogens of cis-1,2-diol moieties, followed by
Sébastien Ladouceur et al.
Inorganic chemistry, 50(22), 11514-11526 (2011-10-04)
Herein we report the synthesis of 4-aryl-1-benzyl-1H-1,2,3-triazoles (atl), made via "Click chemistry" and their incorporation as cyclometallating ligands into new heteroleptic iridium(III) complexes containing diimine (N(^)N) ancillary ligands 2,2'-bipyridine (bpy) and 4,4'-di-tert-butyl-2,2'-bipyridine (dtBubpy). Depending on decoration, these complexes emit from
Adam Noble et al.
Journal of the American Chemical Society, 137(2), 624-627 (2014-12-19)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple
Andrew J Musacchio et al.
Science (New York, N.Y.), 355(6326), 727-730 (2017-02-18)
The intermolecular hydroamination of unactivated alkenes with simple dialkyl amines remains an unsolved problem in organic synthesis. We report a catalytic protocol for efficient additions of cyclic and acyclic secondary alkyl amines to a wide range of alkyl olefins with
Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.
Ladouceur S, et al.
European Journal of Inorganic Chemistry, 2013(30), 5329-5343 (2013)
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