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230197

Sigma-Aldrich

Triethylsilane

Triethylsilane

99%

Synonyme(s) :

NSC 93579, Triethylhydrosilane, Triethylsilicon hydride

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5 G
53,70 €
25 G
55,10 €
100 G
171,00 €
500 G
540,00 €

53,70 €

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Sélectionner une taille de conditionnement

Changer de vue
5 G
53,70 €
25 G
55,10 €
100 G
171,00 €
500 G
540,00 €

About This Item

Formule linéaire :
(C2H5)3SiH
Numéro CAS:
617-86-7
Poids moléculaire :
116.28
Beilstein:
1098278
Numéro CE :
210-535-3
Numéro MDL:
MFCD00009018
Code UNSPSC :
12352103
ID de substance PubChem :
24853781
Nomenclature NACRES :
NA.22

53,70 €

Veuillez contacter notre Service Clients pour connaître la disponibilité de ce produit.
Devis pour commande en gros

Niveau de qualité

200

Essai

99%

Forme

liquid

Pertinence de la réaction

reagent type: reductant

Indice de réfraction

n20/D 1.412 (lit.)

pb

107-108 °C (lit.)

Densité

0.728 g/mL at 25 °C (lit.)

Chaîne SMILES 

CC[SiH](CC)CC

InChI

1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3

Clé InChI

AQRLNPVMDITEJU-UHFFFAOYSA-N

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Catégories apparentées

Application

Catalyst for:
  • Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain
  • Redox initiated cationic polymerization
  • Beckmann rearrangement of cyclododecanone oxime
  • Regioselective reductive coupling of enones and allenes

Catalyst reactivation after catalyst polymerization of styrene

Studies involving the prediction of organosilicon flash points
Used in a study of the reduction of 2-chromanols; syn-selectivity observed with TES.[1]
Versatile reducing agent

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

911208

1-Hydrosilatrane, ≥95%

Pictogrammes

FlameExclamation mark
GHS02,GHS07

Mention d'avertissement

Danger

Mentions de danger

H225,H315,H319,H335

Classification des risques

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

21.2 °F

Point d'éclair (°C)

-6 °C

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
SDBB0807
STBL2015
STBK8590
STBK4815
STBJ8363

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Kelin Li et al.
Organic letters, 8(21), 4711-4714 (2006-10-06)
[reaction: see text] Reduction of C5-substituted 2-hydroxychromans selectively provides 2,4-cis-chromans using large silane reductants and 2,4-trans-chromans using the smaller silane PhSiH(3). The stereochemical outcome has been rationalized on the basis of a Curtin-Hammett kinetic situation arising from hydride delivery to
Zaihui Zhang et al.
Journal of medicinal chemistry, 56(2), 568-583 (2012-12-19)
Stearoyl-CoA desaturase-1 (SCD1) catalyzes de novo synthesis of monounsaturated fatty acids from saturated fatty acids. Studies have demonstrated that rodents lacking a functional SCD1 gene have an improved metabolic profile, including reduced weight gain, lower triglycerides, and improved insulin response.
Sultan Chowdhury et al.
Bioorganic & medicinal chemistry letters, 21(12), 3676-3681 (2011-05-17)
Starting from the oxindole 2a identified through a high-throughput screening campaign, a series of Na(V)1.7 blockers were developed. Following the elimination of undesirable structural features, preliminary optimization of the oxindole C-3 and N-1 substituents afforded the simplified analogue 9b, which
Emma J Ste Marie et al.
Journal of peptide science : an official publication of the European Peptide Society, 24(11), e3130-e3130 (2018-10-26)
Triisopropylsilane (TIS), a hindered hydrosilane, has long been utilized as a cation scavenger for the removal of amino acid protecting groups during peptide synthesis. However, its ability to actively remove S-protecting groups by serving as a reductant has largely been
Meital Bloch et al.
International journal of pharmaceutics, 478(2), 504-516 (2014-12-02)
To increase colonoscopy capability to discriminate benign from malignant polyps, we suggest combining two imaging approaches based on targeted polymeric platforms. Water-soluble cationized polyacrylamide (CPAA) was tagged with the near infrared (NIR) dye IR-783-S-Ph-COOH to form Flu-CPAA. The recognition peptide
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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