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334901

Tetramethylammoniumhydroxid -Lösung

25 wt. % in methanol, solution

Synonym(e):

N,N,N-trimethyl-methanaminium hydroxide, TMAH, TMAOH

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Über diesen Artikel

Lineare Formel:
(CH3)4N(OH)
CAS-Nummer:
Molekulargewicht:
91.15
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
3558708
Concentration:
25 wt. % in methanol
Form:
liquid
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Produktname

Tetramethylammoniumhydroxid -Lösung, 25 wt. % in methanol

vapor pressure

17.5 mmHg ( 20 °C)

Quality Segment

form

liquid

reaction suitability

core: ammonium, reaction type: phase-transfer

concentration

25 wt. % in methanol

impurities

≤10% water, ≤2% chloride

density

0.866 g/mL at 25 °C

functional group

amine

SMILES string

[OH-].C[N+](C)(C)C

InChI

1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1

InChI key

WGTYBPLFGIVFAS-UHFFFAOYSA-M

General description

Tetramethylammonium hydroxide is a strong base used in the o-alkylation of phenolic and carboxylic OH groups.

Tetramethylammonium hydroxide is a quaternary ammonium salt generally used as an anisotropic etchant for silicon due to its high silicon etching rate.

Application

Tetramethylammonium hydroxide solution (25 wt.% solution in methanol) may be used in the synthesis of zirconium oxides via a modified sol-gel method with potential application as catalyst materials in CO hydrogenation.

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Dieser Artikel
426318328251
description

25 wt. % in methanol

description

ACS reagent

description

10 wt. % in H2O

concentration

25 wt. % in methanol

concentration

1.0 M±0.02 M in H2O

concentration

10 wt. % in H2O

Quality Level

200

Quality Level

200

Quality Level

100

form

liquid

form

liquid

form

-

impurities

≤10% water, ≤2% chloride

impurities

-

impurities

-

density

0.866 g/mL at 25 °C

density

1.005 g/mL at 25 °C

density

1.006 g/mL at 25 °C

vapor pressure

17.5 mmHg ( 20 °C)

vapor pressure

-

vapor pressure

17.5 mmHg ( 20 °C)


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Signalwort

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 1 Dermal - STOT SE 1

Zielorgane

Eyes,Central nervous system, Liver,thymus

Lagerklasse

3 - Flammable liquids

Was ist los?

WGK 3

Flammpunkt (°F)

80.6 °F - closed cup

Flammpunkt (°C)

27 °C - closed cup

PSA (Persönliche Schutzausrüstung)

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


Zulassungslistungen

Zulassungslistungen werden hauptsächlich für chemische Produkte erstellt. Für nicht-chemische Produkte können hier nur begrenzte Angaben gemacht werden. Kein Eintrag bedeutet, dass keine der Komponenten gelistet ist. Es liegt in der Verantwortung des Benutzers, die sichere und legale Verwendung des Produkts zu gewährleisten.

67-56-1

CAS No.


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Analysenzertifikate (COA)

Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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