B59500

2-Brombutan

98%

• Synonym(e): sec.-Butylbromid
• Lineare Formel: CH₃CH₂CHBrCH₃
• CAS-Nummer: 78-76-2
• Molekulargewicht: 137.02
• Beilstein: 505949
• EG-Nummer: 201-140-7
• MDL-Nummer: MFCD00000156
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24891883
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: liquid
• Brechungsindex: n20/D 1.437 (lit.)
• bp: 91 °C (lit.)
• Dichte: 1.255 g/mL at 25 °C (lit.)
• SMILES String: CCC(C)Br
• InChI: 1S/C4H9Br/c1-3-4(2)5/h4H,3H2,1-2H3
• InChIKey: UPSXAPQYNGXVBF-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

2-Bromobutane is an alkyl halide. Degradation of 2-bromobutane by reductive dehalogenation in the presence of nickel-aluminum alloy in potassium hydroxide solution has been reported. Gas chromatographic determination of 2-bromobutane in mixture of alkyl bromides has been reported. Stereochemistry of dehydrobromination of 2-bromobutane over KOH-silica has been investigated.

Viscosities of binary mixtures of 2-bromobutane and the isomeric forms of butanol have been evaluated at 298.15 and 313.15K. 2,2-dibromobutane, meso-2,3-dibromobutane and dl-2,3-dibromobutane are formed as major photobromination reaction products, during its reaction with molecular bromine. Smaller yields of 1,2-dibromobutane and 2,2,3-tribromobutane are also obtained in this reaction.

Anwendung

2-Bromobutane may be used in the synthesis of series of non-nucleosides.

Sicherheitshinweise

• Piktogramme: GHS02
• Signalwort: Danger
• H-Sätze: H225,H412
• P-Sätze: P210 - P233 - P240 - P241 - P242 - P273
• Gefahreneinstufungen: Aquatic Chronic 3 - Flam. Liq. 2
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 2
• Flammpunkt (°F): 69.8 °F - closed cup
• Flammpunkt (°C): 21 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter