923451

(PhMPhos)PdCl₂

complex with CH₂Cl₂

• Synonym(e): 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride
• Empirische Formel (Hill-System): C₄₂H₄₈Cl₂FeP₂Pd
• CAS-Nummer: 2768152-18-5
• Molekulargewicht: 847.95
• UNSPSC-Code: 12352101
• NACRES: NA.21

Eigenschaften

• Qualitätsniveau: 100
• Form: powder
• Eignung der Reaktion: reagent type: catalyst; reaction type: Cross Couplings

Beschreibung

Anwendung

(PhMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Sonstige Hinweise

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Sicherheitshinweise

• Piktogramme: GHS08,GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H351
• P-Sätze: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable