901591

18-Crown-6 solution

1.0 M in THF, liquid

• Synonym(e): 1,4,7,10,13,16-Hexaoxacyclooctadecane
• Lineare Formel: C₁₂H₂₄O₆
• CAS-Nummer: 17455-13-9
• UNSPSC Code: 12352005
• NACRES: NA.22
• MDL number: MFCD00005113
• Form: liquid

Eigenschaften

• Produktname: 18-Crown-6 solution, 1.0 M in THF
• form: liquid
• reaction suitability: core: crown ether, reaction type: phase-transfer
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Sustainability features
• concentration: 1.0 M in THF
• density: 0.944 g/mL
• SMILES string: O1CCOCCOCCOCCOCCOCC1
• InChI: 1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2
• InChI key: XEZNGIUYQVAUSS-UHFFFAOYSA-N

Beschreibung

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Phase-transfer catalyst used in a chemoselective reduction of fused tetrazoles with NaBH₄ and potassium hydroxide.

18-Crown-6 may be used to catalyze the N-alkylation of heterocyclic compounds and allylation of functionalized aldehydes.

Additive for greener etherification using KF-alumina.

Additive for greener etherification using KF-alumina.

Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• Gefahrencodes: H225,H302,H318,H335,H336,H351
• Sicherheitshinweise: P202 - P210 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• supp_hazards: EUH019
• Lagerklasse: 3 - Flammable liquids
• Flammpunkt (°F): -2.0 °F
• Flammpunkt (°C): -18.88 °C
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3
• Zielorgane: Central nervous system, Respiratory system